| 2-氨基-6-二茂铁基-4-(2,4-二氯苯基)吡啶-3-腈类化合物的微波合成和结构表征 |
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| 引用本文： | 贾润红,彭菊花,屠树江.2-氨基-6-二茂铁基-4-(2,4-二氯苯基)吡啶-3-腈类化合物的微波合成和结构表征[J].河北科技大学学报,2012,33(1):6-10,13. |
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| 作者姓名： | 贾润红 彭菊花 屠树江 |
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| 作者单位： | 1. 连云港师范高等专科学校初等教育系,江苏连云港,222006
2. 徐州师范大学化学化工学院,江苏徐州,221116 |
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| 基金项目： | 国家自然科学基金，江苏省自然科学基金 |
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| 摘 要： | 标题化合物C24H20Cl2FeN2O2是由2,4-二氯苯甲醛、乙酰二茂铁、氰乙酸乙酯、醋酸铵在水相中微波辐射下反应制得。结构通过单晶X射线衍射法测定,其晶体属单斜晶系、空间群P21/n,a=0.749(3)nm,b=1.136(3)nm,c=2.577(3)nm,α=γ=90°,β=94.021(2)°,V=2.188(1)nm3,相对分子质量Mr=495.17,晶胞密度Dc=1.503g/cm3,Z=4,λ=0.071 073nm,吸收系数μ(Mo Kα)=0.958mm-1,F(000)=1 016,最终偏离因子R=0.079 7,wR=0.161 6。
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| 关 键 词： | 微波辐射 二茂铁取代吡啶 晶体结构 |
| 收稿时间： | 2011/11/1 0:00:00 |
Synthesis of 2-amino-6-ferrocenyl-4-(2,4-dichlorophenyl) pyridine-3-carbonitrile under microwave irradiation and its crystal structure |
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| JIA Run-hong,PENG Ju-hua and TU Shu-Jiang.Synthesis of 2-amino-6-ferrocenyl-4-(2,4-dichlorophenyl) pyridine-3-carbonitrile under microwave irradiation and its crystal structure[J].Journal of Hebei University of Science and Technology,2012,33(1):6-10,13. |
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| Authors: | JIA Run-hong PENG Ju-hua and TU Shu-Jiang |
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| Institution: | 1.Elementary Education Department,Lianyungang Teacher’s College,Lianyungang Jiangsu 222006,China;2.College of Chemistry and Chemical Engineering,Xuzhou Normal University,Xuzhou Jiangsu 221116,China) |
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| Abstract: | The title compound C24H20Cl2FeN2O2 was synthesized by the reaction of 2,4-dichlorobenzaldehyde,acetylferrocene,ethyl cyanoacetate,and ammonium acetate in aqueous medium under microwave irradiation.Its crystal structure was determined by single-crystal X-ray diffraction.The crystal is of monoclinic and space group P21/n,a=0.749(3) nm,b=1.136(3) nm,c=2.577(3) nm,α=γ=90°,β=94.021(2)°,V=2.188(1) nm3,Mr =495.17,Dc=1.503 g/cm3,Z=4,λ=0.071 073 nm,μ(Mo Kα)=0.958 mm-1,F(000) =1 016,R=0.079 7,and wR=0.161 6. |
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| Keywords: | microwave irradiation ferrocenyl-pyridine derivatives crystal structure |
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