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十二烷基苯磺酸钠表面膜的扩张粘弹性质研究
引用本文:程栋,丁洪流,陆维昌,刘启贞,陈邦林.十二烷基苯磺酸钠表面膜的扩张粘弹性质研究[J].华东师范大学学报(自然科学版),2005,2005(4):37-42.
作者姓名:程栋  丁洪流  陆维昌  刘启贞  陈邦林
作者单位:华东师范大学,化学系,上海,200062
摘    要:研究了不同浓度十二烷基苯磺酸钠(SDBS)溶液在气-液表面上的扩张粘弹性质,讨论了扩张模量、扩张粘度、扩张模量的相角随频率的变化规律,实验结果表明,其表面膜的微观弛豫过程主要受扩散弛豫类型控制.此外,本文还讨论了温度、浓度等因素对SDBS表面扩张性质的影响,研究了它们的内在联系.

关 键 词:界面扩张粘弹性  扩张模量  十二烷基苯磺酸钠  微观弛豫类型  界面扩张粘弹性  扩张模量  十二烷基苯磺酸钠  微观弛豫类型
文章编号:1000-5641(2005)04-0037-06
收稿时间:2004-10
修稿时间:2004年10月1日

Dilatational Viscoelasticity of Surface Film of SDBS at Gas-Water Interface(Chinese)
CHENG Dong,DING Hong-liu,LU Wei-chang,LIU Qi-zhen,CHEN Bang-lin.Dilatational Viscoelasticity of Surface Film of SDBS at Gas-Water Interface(Chinese)[J].Journal of East China Normal University(Natural Science),2005,2005(4):37-42.
Authors:CHENG Dong  DING Hong-liu  LU Wei-chang  LIU Qi-zhen  CHEN Bang-lin
Institution:Department of Chemistry, East China Normal University, Shanghai 200062,China
Abstract:The dilational viscoelasticity properties of gas-water interface of SDBS were investigated.The dependence of dilational modulus,dilational viscosity and phase angle on dilational frequency was expoun- ded.The results showed that the microscopic relaxation model of the surface film was decided by diffusion- control model.Besides,the influence of temperature and concentration to the interfacial dilational properties of SDBS was also discussed,and the intrinsic relation between them was studied.
Keywords:interfacial dilational viscoelasticity property  dilational modulus  Sodium Dodecyl Benzene Sulphonate  microscopic relaxation model
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