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表面活性剂胶束对Belousov-Zhabotinsky振荡反应的影响
引用本文:罗冬丽,刘凡,聂丽,唐典勇,张云涛,张元勤.表面活性剂胶束对Belousov-Zhabotinsky振荡反应的影响[J].四川大学学报(自然科学版),2009,46(3):761-768.
作者姓名:罗冬丽  刘凡  聂丽  唐典勇  张云涛  张元勤
作者单位:1. 西华师范大学化学化工学院,南充,637002
2. 乐山师范学院化学与生命科学学院,乐山,614004
基金项目:乐山市科技局重点资助课题、四川省学术和技术带头人培养基金
摘    要:采用我们自己开发设计的无纸记录仪器,从铈离子催化的经典B-Z振荡反应出发,探讨了三种不同类型的表面活性剂即阳离子表面活性剂CTAB,非离子表面活性剂Brij35和阴离子表面活性剂SDS对其振荡行为的影响. 实验结果表明:当表面活性剂浓度大于其在该溶液中的临界胶束浓度时,都会对振荡反应造成一定的影响,不同的表面活性剂其影响程度的大小和趋势也有所不同.

关 键 词:B-Z振荡反应  CTAB  Brij35  SDS

The effect of cationic anionic and nonionic surfactants on the Belousov-Zhabotinsky reaction
LUO Dong-LI,LIU Fan,NIE Li,TANG Dian-Yong,ZHANG Yun-Tao and ZHANG Yuan-Qin.The effect of cationic anionic and nonionic surfactants on the Belousov-Zhabotinsky reaction[J].Journal of Sichuan University (Natural Science Edition),2009,46(3):761-768.
Authors:LUO Dong-LI  LIU Fan  NIE Li  TANG Dian-Yong  ZHANG Yun-Tao and ZHANG Yuan-Qin
Institution:College of Chemistry and Chemical Engineering, China West Normal University;Department of Chemistry and Life Science, Leshan Teachers College;Department of Chemistry and Life Science, Leshan Teachers College;Department of Chemistry and Life Science, Leshan Teachers College;Department of Chemistry and Life Science, Leshan Teachers College;Department of Chemistry and Life Science, Leshan Teachers College
Abstract:This paper has reported the effects of the cationic surfactant CTAB, nonionic surfactant Brij35 and anionic surfactant SDS on the oscillations of the ceriu-catalyzed Belousov-Zhabotinsky(BZ) type oscillating.The experimental results indicated that there was a change in the oscillation behavior in the presence of above-mentioned surfactants above their critical micelle concentrations.For different surfactants,the influence was different.
Keywords:B-Z oscillatory reaction  CTAB  Brij35  SDS
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