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桥链中含氮,硫杂原子二酰胺的质谱研究
引用本文:黄枢,许建光.桥链中含氮,硫杂原子二酰胺的质谱研究[J].四川大学学报(自然科学版),1996,33(3):294-301.
作者姓名:黄枢  许建光
作者单位:湖北襄樊市华中制药厂
摘    要:对四类桥链中含氮、硫原子的二酰胺的质谱进行了研究,揭示了经们的破裂规律;指各类之间质谱的异同;推论了一些特征离子的结构和可能的形成机理。

关 键 词:二酰胺  质谱  噻吡Weng离子  噻ZhuoWeng离子

STUDY ON THE MASS SPECTROMETRY OF DIACYLAMIDES WITH BRIDGED CHAINS CONTAINING NITROGEN AND/OR SULFUR ATOMS
Huang Shu, Yan Yunjiang, Tian Baozhi.STUDY ON THE MASS SPECTROMETRY OF DIACYLAMIDES WITH BRIDGED CHAINS CONTAINING NITROGEN AND/OR SULFUR ATOMS[J].Journal of Sichuan University (Natural Science Edition),1996,33(3):294-301.
Authors:Huang Shu  Yan Yunjiang  Tian Baozhi
Institution:Huang Shu; Yan Yunjiang; Tian Baozhi(Department of Chemistry)Xiu Jianguang (Analytical and Testing Center)
Abstract:This paper reported a study on the mass spectrometry of four kinds of diacylamides with bridged chains containing nitrogen and/or sulfur atoms. Their cleavage rules as well as the similarities and differences between the kinds of the compounds were revealed. The structures and the probable mechanisms of formation of some characteristic ions were deduced.
Keywords:diacylamide  mass spetrometry  thiopyrilium ion  thiotropylium ion
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