| N-(2,6-二烷基苯基)-2-呋喃甲酰胺镍配合物的合成及其催化甲基丙烯酸甲酯的聚合 |
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| 引用本文： | 张丹枫,赵平,黄葆同.N-(2,6-二烷基苯基)-2-呋喃甲酰胺镍配合物的合成及其催化甲基丙烯酸甲酯的聚合[J].华东理工大学学报(自然科学版),2012,38(1):1-5,27. |
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| 作者姓名： | 张丹枫 赵平 黄葆同 |
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| 作者单位： | 1. 华东理工大学材料科学与工程学院,上海市先进聚合物材料重点实验室,上海200237
2. 华东理工大学材料科学与工程学院,上海市先进聚合物材料重点实验室,上海200237／中国科学院长春应用化学研究所,长春130022 |
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| 基金项目： | 上海市重点学科和重点实验室项目，中国石油天然气股份有限公司科技风险创新研究项目基金，教育部留学回国人员科研启动基金，华东理工大学校基金 |
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| 摘 要： | 以呋喃甲酸、5-叔丁基-2-呋喃甲酸为起始物,在PCl3作用下,与苯胺、2,6-二烷基苯胺反应(烷基为乙基、异丙基),合成了4个N-(2,6二-烷基苯基)-5-叔丁基-2-呋喃甲酰胺有机配体,同时以N-(2,6-二乙基苯基)-5-叔丁基-2-呋喃甲酰胺与trans-NiCl(Ph)(PPh3)2]反应合成了1个新的呋喃甲酰胺镍配合物,并采用核磁共振(1H-NMR)、红外光谱(IR)、质谱(MS)及元素分析(EA)对它们的结构进行了表征。以该配合物为催化剂,在甲基铝氧烷(MAO)作用下对甲基丙烯酸甲酯进行了催化聚合,以配合物中等的催化活性得到了富含间规结构的聚甲基丙烯酸甲酯(PMMA)。
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| 关 键 词： | 呋喃甲酰胺 镍配合物 后过渡金属催化剂 甲基丙烯酸甲酯 |
Synthesis of N-（2,6-Dialkylphenyl）-2-Furoamide Ni Complex and Its Catalytic Behavior for Polymerization of Methyl Methacrylate |
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| ZHANG Dan-feng,ZHAO Ping,HUANG Bao-tong.Synthesis of N-（2,6-Dialkylphenyl）-2-Furoamide Ni Complex and Its Catalytic Behavior for Polymerization of Methyl Methacrylate[J].Journal of East China University of Science and Technology,2012,38(1):1-5,27. |
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| Authors: | ZHANG Dan-feng ZHAO Ping HUANG Bao-tong |
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| Institution: | 1,2(1.Shanghai Key Laboratory of Advanced Polymeric Materials,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China;2.Changchun Institute of Applied Chemistry,Chinese Academy of Science,Changchun 130022,China) |
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| Abstract: | Under the effect of PCl3,four compounds of N-(2,6-dialkylphenyl)-5-butyl-2-furoamides(alkyl: ethyl,isopropyl) were synthesized by reaction of 3-furoic acid,5-butyl-2-furoic acid with aniline,2,6-dialkyl aniline,respectively.A novel nickel complex,N-(2,6-diethylphenyl)-5-butyl-2-furoamide Ni(Ph)(PPh3) was prepared via corresponding ligand and trans-NiCl(Ph)(PPh3)2].The structures of furoamide compounds and the Ni complex were characterized by 1H-NMR,IR,MS and EA.In the presence of methylaluminoxane(MAO) as cocatalyst,the nickel complex exhibited a mediate activity for the polymerization of methyl methacrylate(MMA) and syndiotactic-rich poly(methyl methacrylate) was obtained. |
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| Keywords: | furoamide nickel complex late transition metal catalyst methyl methacrylate |
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