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石油馏分的物性关联
引用本文:常振明,吴喜忠,李承烈.石油馏分的物性关联[J].华东理工大学学报(自然科学版),1993(6).
作者姓名:常振明  吴喜忠  李承烈
作者单位:华东化工学院石油加工研究所 (常振明,吴喜忠),华东化工学院石油加工研究所(李承烈)
摘    要:通过对石油馏分一次加工油和二次加工油分子量的考察,优选了分子量和沸点(T)、相对密度,特性因素(UOPK)的关联式。对大量纯化合物的T和碳原子数的回归,得到了T、碳数和UOPK的函数关联式。将石油馏分按碳数大小分成若干个虚拟组分,对每个碳数虚拟组分赋以分子量、UOPK、硫、氮含量、摩尔流率、碳原子数流率等数值,即可在加氢等工艺预测性动力学模型建立中,预测产品性质。

关 键 词:石油馏分  分子量  结构族组成  虚拟组分  流率

Correlation of Physical and Chemical Properties of Petroleum Fractions
Chang Zhenming,Wu Xizhong and Li Chenglie.Correlation of Physical and Chemical Properties of Petroleum Fractions[J].Journal of East China University of Science and Technology,1993(6).
Authors:Chang Zhenming  Wu Xizhong and Li Chenglie
Institution:Petroleum Processing Research Center
Abstract:Good correlated equations about molecular weight has been selected with the experimental data for petroleum fractions from distillation and other processing. Related equations for boiling points, carbon numbers and characteristic factor K were regressed from the informations of a large number of pure hydrocarbon compounds. Petroleum fractions were considered to be broken down into carbon number pseudocomponents. In this paper, they were further characterized by determining their molecular weight, characterized factor K, sulfur and nitrogen contents and mole and carbon number flow rate in addition to the aromatic carbon, naphthenic carbon and paraffinic carbon fractions. These charaterization steps were presented and compared. These rusults can be applied for predicating properties of various products in kinetic modelling of hydrogenation and other processes.
Keywords:petroleum fractions  molecular weight  structural composition  pseudocomponent  flow rate  
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