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苯酚的溶剂萃取和萃淋树脂吸附
引用本文:高浩其,苏元复.苯酚的溶剂萃取和萃淋树脂吸附[J].华东理工大学学报(自然科学版),1991(3).
作者姓名:高浩其  苏元复
作者单位:华东化工学院化学工程研究所 (高浩其),华东化工学院化学工程研究所(苏元复)
摘    要:测定了N503、TBP和TRPO萃取苯酚的平衡曲线。发现TBP和TRPO萃取平衡线可用Langmuir型方程表示,20℃时的萃取平衡常数分别为157和540。N503萃取苯酚的平衡线呈S形,因此低浓度时萃取脱酚比较困难。含TBP和TRPO的萃淋树脂吸附苯酚的平衡性能与萃取相似,其温度引起的变化和溶剂萃取完全相同,但同温度下的平衡常数略小。讨论并比较了不同萃取剂萃取和萃淋树脂吸附的性能,认为萃淋树脂有其优越性。

关 键 词:苯酚  吸附  溶剂萃取  废水处理  萃淋树脂

Solvent Extraction and Adsorption by Extracting Resins of Phenol
Gao Haoqi and Su Yuanfu.Solvent Extraction and Adsorption by Extracting Resins of Phenol[J].Journal of East China University of Science and Technology,1991(3).
Authors:Gao Haoqi and Su Yuanfu
Institution:Chemical Engineering Research Center
Abstract:The equilibria of extraction of phenol by N503, TBP and TRPO and adsorption of phenol by TBP and TRPO extracting resins were studied respectively and compared. It is difficult to reduce phenol in industrial effluents to 1 ppm by extraction with N503. The extracting resin method may be a attractive alternative to the combined process of extraction and adsorption. Its advantages over extraction consist in very low residual phenol content in treated liquor and simple equipments and over adsorption by activated carbon in high capacity.
Keywords:phenol  adsorption  solvent extraction  wastewater treatment  extracting resin  
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