|
|||||
|
|
| 氢键型层状有机超分子晶体C144H10O5 | |
| 引用本文： | 张翠乔,郝宝润,汪洋林,韦庆婷,付峰,王继武.氢键型层状有机超分子晶体C144H10O5[J].延安大学学报(自然科学版),2008,27(1):48-51. |
| 作者姓名： | 张翠乔 郝宝润 汪洋林 韦庆婷 付峰 王继武 |
| 作者单位： | 1. 延安大学,化学与化工学院,陕西省化学反应工程重点实验室,陕西延安716000 2. 铜川市二中,陕西铜川,727000 3. 陕西富县北道德中学,陕西富县,727502 |
| 摘 要： | 利用柔性配体（4，4’-二苯醚二甲酸，4，4’-oxydibenzoic acid，H20ba）与Zn（N03）2反应得到了一种新型有机晶体C144H10O5，通过元素分析、x-射线单晶衍射等技术测定了晶体结构，结果表明，配合物属单斜晶系，空间群P2，们n=5．7204（14）A，b=27．473（7）A，c=14．821（4）A，β =90°；z=8；R=0．0555。在有机晶体中，紧邻分子单元通过氢键作用在b轴形成一维链；链间籍氢键相互作用拓展为三维超分子网络。 |
| 关 键 词： | 4 4’-二苯醚二甲酸(4 4’-oxydibenzoic ACID H2oba) 晶体结构 氢键 超分子晶体 |
| 文章编号： | 1004-602X(2008)01-0048-04 |
| 修稿时间： | 2007年12月8日 |
The Organic Supramolecular Layer C14H10O5 via Hydrogen Bonds |
|
| ZHANG Cui-qiao,HAO Bao-run,WANG Yang-lin,WEI Qing-ting,FU Feng,WANG Ji-wu.The Organic Supramolecular Layer C14H10O5 via Hydrogen Bonds[J].Journal of Yan'an University(Natural Science Edition),2008,27(1):48-51. | |
| Authors: | ZHANG Cui-qiao HAO Bao-run WANG Yang-lin WEI Qing-ting FU Feng WANG Ji-wu |
| Institution: | ZHANG Cui - qiao, HAO Bao - run, WANG Yang - lin, WEI Qing - ting, FU Feng , WANG Ji - wu ( 1. Key Laboratory of Chemical Reaction Engineering of Shaanxi Province, Department of Chemistry and Chemical Engineering , Yanan University, Yanan Shaanxi 716000; 2. The NO. 2 Middle School of Tong chuan, Shaanxi 727000; 3. The Beidaode Middle School of Fuxian County, Yanan Shaanxi 727502) |
| Abstract: | A novel organic supramolecular complex C144H10O5 has been prepared from the reaction of flexible bridging ligand （4,4＇ - oxydibenzoic acid, H2 oba） with Zn （ NO3 ） 2 and structurally characterized by IP, single crystal X - ray diffraction. Crystal structural analysis reveals that the complex is monoclinic, with space group P2 （ 1 ）/c, a = 5.7204（ 14）A,b =27. 473（7） A,c = 14. 821 （4） A,β =90° ;Z =8 ;R =0. 0555. The crystal structure of complex is the ligand molecular. The adjacent constructure unit extended to 1 -D chain in the b axis by hydrogen bonds. And the 1 - D chain further extended to 2 - D layers constructure van hydrogen bonding interactions along a axis. Furhtermore, the three -dimensional framework were formed through hydrogen bonding. |
| Keywords: | 4 4＇- oxydibenzoic acid H2oba Crystal Structure hydrogen bonds supramolecular complex ／ |
| 本文献已被 维普 万方数据 等数据库收录！ | |