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电化学方法快速测定尿酸的应用研究
引用本文:张英,张智彦,马华,刘伟.电化学方法快速测定尿酸的应用研究[J].四川理工学院学报(自然科学版),2009,22(4):85-87.
作者姓名:张英  张智彦  马华  刘伟
作者单位:四川理工学院化学与制药工程学院,四川,自贡,643000
摘    要:采用恒电位沉积方法制备了EDTA修饰玻碳电极,并考察了尿酸(UA)在修饰电极上的电化学行为。在优化的实验条件下,UA在修饰电极上的氧化峰电流显著增强,UA在8.0×10~(-7)~8.0×10~(-5)mol·L~(-1)浓度范围内与其氧化峰电流成良好的线性关系。该电极制备简单,响应快,使用方便,用于尿样中UA的检测,效果良好。

关 键 词:尿酸  EDTA  恒电位沉积  修饰电极

Study on the Elecreochemical Detection of Uric Acid in Urine Sample
ZHANG Ying,ZHANG Zhi-yan,MA Hua,LIU Wei.Study on the Elecreochemical Detection of Uric Acid in Urine Sample[J].Journal of Sichuan University of Science & Engineering:Natural Science Editton,2009,22(4):85-87.
Authors:ZHANG Ying  ZHANG Zhi-yan  MA Hua  LIU Wei
Institution:School of Chemical & Pharmaceutical Engineering;Sichuan University of Science & Engineering;Zigong 643000;China
Abstract:Glassy carbon electrode modified with EDTA is fabricated by potentiostatic technique.The modified electrode is applied to determination of uric acid(UA).The resulting electrode showes excellent electrocatalytic activity towards oxidation of UA.Good linearity is obtained in the concentration range of 8.0×10~(-7)~8.0×10~(-5) mol·L~(-1) under the optimum operations. Moreover,the proposed sensor shows simple preparation,rapid response and convenient use,and it has been applied to the determination of uric acid in practical urine samples with good results.
Keywords:EDTA
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