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β-环糊精/TiO2复合光催化剂制备及光催化性能探讨
引用本文:余国贤,张晓慧,晋梅,路平,LU Ping.β-环糊精/TiO2复合光催化剂制备及光催化性能探讨[J].江汉大学学报(自然科学版),2011,39(2):27-30,46.
作者姓名:余国贤  张晓慧  晋梅  路平  LU Ping
作者单位:江汉大学化学与环境工程学院,湖北武汉,430056
基金项目:湖北省自然科学基金资助项目(2003ABA090)
摘    要:研究用硅烷偶联剂KH560做交联剂,以β-环糊精(β-CD)对TiO2固体表面进行改性,制备β-CD/TiO2复合材料.通过钛含量测定、红外和热重分析对β-CD/TiO2复合材料进行了表征.以甲基橙溶液为研究对象,分别考察了β-CD/TiO2复合材料和纯TiO2对甲基橙的光催化降解能力.结果表明:制得的β-CD/TiO...

关 键 词:β-环糊精  TiO2  甲基橙  光催化脱色

Preparation and Photocatalytic Performance of β-cyclodextrin/TiO2 Complex Catalyst
YU Guo-xian,ZHANG Xiao-hui,JIN Mei,LU Ping.Preparation and Photocatalytic Performance of β-cyclodextrin/TiO2 Complex Catalyst[J].Journal of Jianghan University:Natural Sciences,2011,39(2):27-30,46.
Authors:YU Guo-xian  ZHANG Xiao-hui  JIN Mei  LU Ping
Institution:YU Guo-xian,ZHANG Xiao-hui,JIN Mei,LU Ping(School of Chemistry and Environmental Engineering,Jianghan University,Wuhan 430056,Hubei,China)
Abstract:β-cyclodextrin/TiO2(β-CD/TiO2) complex catalyst was prepared via surface modification of TiO2 with β-cyclodextrin using silane coupling agent as the cross-linking agent.The structure and properties of β-CD/TiO2 was characterized by gravimetric analysis in determination of titanium content,fourier transform infrared spectrophotometry(FT-IR) and differential thermal analyzer(DTA).The photocatalytic performances of β-cyclodextrin/TiO2 and TiO2 were investigated by using methyl orange solution as objcet,respectively.The characterization results showed the content of TiO2 in β-CD/TiO2 complex sample was 75%.The photocatalytic performance results demonstrated β-CD/TiO2 complex catalyst could give the decoloration rate to methyl orange solution of 90% under the high pressure mercury lamp for 3.5 h,which is 1.7 times larger than that of TiO2.
Keywords:β-cyclodextrin  TiO2  methyl orange solution  photocatalytic decoloration
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