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Quasi—solid—state nanocrystalline TiO2 solar cells using gel network polymer electrolytes based on polysiloxanes
作者姓名:LIWeiying  KANGJunjie  LIXueping  FANGShibi  LINYuan  WANGGuiqiang  XIAOXurui
作者单位:CenterforMolecularScience,InstituteofChemistry,ChineseAcademyofSciences,Beijing100080,Chian
基金项目:国家重点基础研究发展计划(973计划),中国科学院知识创新工程项目 
摘    要:A quasi-solid-state dye-sensitized manocrystal-line porous TiO2 film solar cell was fabricated using a novel gel network polymer electrolyte based on polysiloxanes with both polyethylene oxide internal plasticized side chains and quaternary ammonium groups.The cell exhibited better photoelectrical conversion performance under 60 mW/cm^2 irradiation.The short photocurrnt (Isc) of 5.0mA/cm^2 and open voltage(Voc) of 0.68V were achieved,and the energy conversion efficiency(η) and fill factor (ff) were 3.4% and 0.60,respectively.

关 键 词:类固态TiO2太阳能电池  凝胶网状聚合体电解液  染色敏化  二氧化钛薄膜
收稿时间:2002-09-05
修稿时间:2002-12-09

Quasi-solid-state nanocrystalline TiO2 solar cells using gel network polymer electrolytes based on polysiloxanes
LIWeiying KANGJunjie LIXueping FANGShibi LINYuan WANGGuiqiang XIAOXurui.Quasi-solid-state nanocrystalline TiO2 solar cells using gel network polymer electrolytes based on polysiloxanes[J].Chinese Science Bulletin,2003,48(7):646-648.
Authors:Weiying Li  Junjie Kang  Xueping Li  Shibi Fang  Yuan Lin  Guiqiang Wang  Xurui Xiao
Institution:LI Weiying, KANG Junjie, LI Xueping, FANG Shibi, LIN Yuan, WANG Guiqiang & XIAO Xurui Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
Abstract:A quasi-solid-state dye-sensitized nanocrystal-line porous TiO2 film solar cell was fabricated using a novel gel network polymer electrolyte based on polysiloxanes with both polyethylene oxide internal plasticized side chains and quaternary ammonium groups. The cell exhibited better photoelectrical conversion performance under 60 mW/cm2 irradiation. The short photocurrent (Isc) of 5.0 mA/cm2 and open voltage (Voc) of 0.68 V were achieved, and the energy conversion efficiency (h ) and fill factor (ff) were 3.4% and 0.60, respectively.
Keywords:gel network polymer electrolytes  nanocrystalline porous TiO2 film  dye-sensitized  solar cell    
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