Reverse atom transfer radical polymerization of methyl methacrylate initiated by AIBN/FeCl<sub>3</sub>/isophthalic acid system期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Reverse atom transfer radical polymerization of methyl methacrylate initiated by AIBN/FeCl₃/isophthalic acid system

Authors:	ZHANG Guosheng ZHU Shenmin YAN Deyue

Institution:	(1)School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240 ,China

Abstract:	The reverse ATRP of MMA using AIBN/FeCl₃/ isophthalic acid as the initiating system was successfully performed. The new initiating system can be used to synthesize PMMA with high molecular weight and narrow polydis- persity index. The polymerization shows ‘living’/controlled characteristics. Compared with other initiating system used in reverse ATRP, the easy availability and non-toxicity of isophthalic acid make it very attractive.

Keywords:	reverse ATRP MMA nontoxic ligand AIBN/FeCl₃/ isophthalic acid system

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