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Comprehensive study on genetic pathways and parent materialsof secondary biogenic gas in coalbeds
基金项目:Sample collection was supported by relevant coal departments and Professor Tang Xiuyi. Dr. Zhang Xiaojun took part in some sampling. The authors greatly appreciate their help and support. This study was supported by the National Natural Science Foundation of China (41172107), the National Basic Research Program of China (2002CB211701) and the Program of State Key Laboratory of Earth Surface Processes and Resource Ecology (2011-zy-04).
摘    要:The types of substances in coal rock used by microbes,the specific ways in which microbes produce secondary biogenic gas(SBG)and whether substances exist in the coal seam for the formation of a large amount of SBG are important basic scientific issues.This paper conducts a systematic and comprehensive research study on the above issues using methods such as the isotopic tracing of gas,the analysis of coal organic geochemistry,and gas-producing simulation experiments of coal.Results show that the formation of SBG is by the microbial reduction of CO2and the SBG-producing coal seam undergoes microbial degradation.The thermogenic heavy gaseous hydrocarbons have also been degraded by microorganisms and possibly transformed into microbialoriginated CO2.A large amount of CO2,a relatively large amount of H2and a certain amount of heavy gaseous hydrocarbons may form in the thermal evolution of coal.These substances and the microbial-originated CO2and coal seam water can finally become parent materials of SBG.These components are rich in coal seams of medium–low thermal evolution,which should be the main coal seams for SBG formation and exploration.

关 键 词:Secondary  biogenic  gas  Geneticpathway  Parent  materials  Isotopic  tracing  Coalbed  gas

Comprehensive study on genetic pathways and parent materials of secondary biogenic gas in coalbeds
Authors:Mingxin Tao  Wanchun Wang  Zhongping Li  Yuzhen Ma  Jing Li  Xiaobin Li
Institution:1. State Key Laboratory of Earth Surface Processes and Resource Ecology/College of Resources Science and Technology, Beijing Normal University, Beijing, 100875, China
2. Lanzhou Petroleum Resources Research Center, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou, 730000, China
Abstract:The types of substances in coal rock used by microbes, the specific ways in which microbes produce secondary biogenic gas (SBG) and whether substances exist in the coal seam for the formation of a large amount of SBG are important basic scientific issues. This paper conducts a systematic and comprehensive research study on the above issues using methods such as the isotopic tracing of gas, the analysis of coal organic geochemistry, and gas-producing simulation experiments of coal. Results show that the formation of SBG is by the microbial reduction of CO2 and the SBG-producing coal seam undergoes microbial degradation. The thermogenic heavy gaseous hydrocarbons have also been degraded by microorganisms and possibly transformed into microbial-originated CO2. A large amount of CO2, a relatively large amount of H2 and a certain amount of heavy gaseous hydrocarbons may form in the thermal evolution of coal. These substances and the microbial-originated CO2 and coal seam water can finally become parent materials of SBG. These components are rich in coal seams of medium–low thermal evolution, which should be the main coal seams for SBG formation and exploration.
Keywords:Secondary biogenic gas  Genetic pathway  Parent materials  Isotopic tracing  Coalbed gas
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