苯基卟啉衍生物及其锌、锰配合物的合成、光物理性能及电化学性质

为寻求更好的苯基卟啉类光电材料,以吡咯和取代苯甲醛为原料,通过改进的Alder法合成了3种苯基卟啉衍生物及其锌、锰配合物,对目标化合物进行了FT-IR、MS、XPS和元素分析等表征,并测试了化合物的紫外、荧光光谱,探讨了其光物理性能和电化学性质.结果表明：通过改进的合成方法,苯基卟啉衍生物及其锌、锰配合物合成简单、收率高且其光电性能良好.

Synthesis,Photophysical and Electrochemical Properties of Phenylporphyrin Derivatives and Their Zinc,Manganese Complexes

With the intention to obtain highly efficient optic-electronic materials,three phenylporphyrin derivatives and their zinc,manganese complexes were synthesized by an improved Alder methods using pyrrole and substituted benzaldehydes as raw materials.The structures of these compounds were characterized by FT-IR,MS,XPS and element analysis,and their electronic absorption,fluorescence and eletrochemical properties have been systematically investigated.The phenylporphyrin derivatives and their zinc,manganese com...