肾上腺素的单扫描示波极谱滴定及Cu~(2+)和肾上腺素的化学反应动力学研究 |
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摘 要: | 利用单扫描示波极谱法研究了不同条件下Cu(2+)与肾上腺素间的化学反应。基于其络合反应建立了肾上腺素的示波极谱滴定法;基子Zn(2+)存在与下Cu(2+)与肾上腺素的氧化还原反应,测定了有关的动力学参数,提出了可能的反应机理和速率表达式。
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关 键 词: | 肾上腺素,示波极谱滴定,化学反应动力学 |
SINGLE SWEEP OSCILLOPOLAROGRAPHIC TITRATION OF ADRENALINE AND THE KINETICS OF THE REACTION BETWEEN Cu (II)AND ADRENALINE |
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Authors: | Kang Xiao-feng Guo Jin-bao |
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Institution: | Department of Chemistry and Chemicd Engineering |
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Abstract: | The Chemical reaction of Cu(II)with adrenaline under the various conditions were investigated by linear sweep polarography. Oscllopolarographic titration method based on compleking reaction have been developed for the determination of adrenaline. The reaction mechanisms were studied and some kinetic parameters related to the oxidahon-reduction reaction between on(II)and adrendline under action of Zn(II)were measured. |
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Keywords: | Adrenaline Oscillopolarographic titration kinetics of reaction |
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