| HMO理论教学难点剖析——波函数多种形式的等效性 |
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| 引用本文： | 黄荣谊,陈友存.HMO理论教学难点剖析——波函数多种形式的等效性[J].安庆师范学院学报(自然科学版),2011,17(2):101-104. |
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| 作者姓名： | 黄荣谊 陈友存 |
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| 作者单位： | 安庆师范学院 化学化工学院,功能配合物安徽省重点实验室,安庆 246011 |
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| 基金项目： | 安徽高校省级优秀青年人才基金项目(2010SQRL108ZD)资助 |
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| 摘 要： | 作为HMO理论教学难点之一,共轭分子波函数多种形式的等效性较为抽象,很多教材讲解不深,学生很难理解把握。本文就这一内容进行了详细分析,给出了不同拓扑结构和对称面下的分子轨道波函数的所有表示形式,并探讨了各分子轨道波函数的多种表示形式的等效性,有利于加深学生对HMO理论和波函数的认识和理解,提高教学效果。
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| 关 键 词： | HMO理论 共轭分子 波函数 分子图 |
Equivalency of the Various Forms of Wave Function as a Difficult Teaching Point in HMO Theory |
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| HUANG Rong-yi,CHEN You-cun.Equivalency of the Various Forms of Wave Function as a Difficult Teaching Point in HMO Theory[J].Journal of Anqing Teachers College(Natural Science Edition),2011,17(2):101-104. |
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| Authors: | HUANG Rong-yi CHEN You-cun |
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| Institution: | HUANG Rong-yi,CHEN You-cun(Anhui Key Laboratory of Functional Coordination Compounds,School of Chemistry and Chemical Engineering,Anqing Teachers College,Anqing 246011) |
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| Abstract: | As one of the difficult teaching points in HMO theory,the equivalency of the various forms of wave function in conjugated molecule is very abstract for study,and is difficult to understand for students.In this paper,this content is analyzed in detail,and all forms of the π-molecular orbital wave function are given under different topology and symmetry plane.At the same time,the equivalency of the different forms of π molecular orbital wave function is investigated.This work will help students to deepen the awareness and understanding of HMO theory and wave function and improve teaching effect. |
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| Keywords: | HMO theory conjugated molecule wave function molecular graph |
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