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聚醋酸乙烯/蒙脱土复合乳液的制备及性能
引用本文:杨瑞成,成佳辉,陈奎,郧栋,靳塞特.聚醋酸乙烯/蒙脱土复合乳液的制备及性能[J].兰州理工大学学报,2009,35(1).
作者姓名:杨瑞成  成佳辉  陈奎  郧栋  靳塞特
作者单位:1. 兰州理工大学,甘肃省有色金属新材料重点试验室, 甘肃,兰州,730050;兰州理工大学,有色金属合金及加工教育部重点实验室,甘肃,兰州,730050
2. 兰州理工大学,甘肃省有色金属新材料重点试验室,甘肃,兰州,730050
基金项目:甘肃省高校研究生导师基金 
摘    要:利用半连续乳液聚合方法制备涂料用聚醋酸乙烯/蒙脱土复合乳液,通过FT-IR、XRD对该复合乳液的结构进行表征,研究蒙脱土质量分数对乳液固含量、硬度、耐水性的影响.结果表明,聚醋酸乙烯很好地插层于蒙脱土片层当中,获得插层型聚醋酸乙烯/蒙脱土纳米乳液;当蒙脱土质量分数为7%时,聚醋酸乙烯/蒙脱土纳米乳液涂膜硬度从2 B提高到3 H,固体质量分数达到33.2%,而且涂膜静置于水中100 h不脱落,相对一般聚醋酸乙烯乳液,其耐水性获得极大的提高.

关 键 词:聚醋酸乙烯  蒙脱土  涂料  纳米乳液

Preparation of polyvinyl acetate/montmorillonite composite latex and it's property
YANG Rui-cheng,CHENG Jia-hui,CHEN Kui,YUN Dong,JIN Sai-te.Preparation of polyvinyl acetate/montmorillonite composite latex and it''s property[J].Journal of Lanzhou University of Technology,2009,35(1).
Authors:YANG Rui-cheng  CHENG Jia-hui  CHEN Kui  YUN Dong  JIN Sai-te
Institution:1.State Key Lab.of Gansu Advanced Non-ferrous Metal Materials;Lanzhou Univ.of Tech.;Lanzhou 730050;China;2.Key Lab.of Non-ferrous Metal Alloys;The Ministry of Education;China
Abstract:Polyvinyl acetate/montmorillonite composite latex as a kind of coating was prepared by using semi-continuous polymerization,its structure was characterized by means of FT-IR and XRD,and the influence of mass-fraction of the montmorillonite on the content,hardness,and moistureproof ability of the solid-particle in the latex was investigated.The result showed that the polyvinyl acetate was well intercalated into the layered montmorillonite so that a type of intercalated polyvinyl acetate/montmorillonite nano-...
Keywords:polyvinyl acetate  montmorillonite  coating  nano-latex  
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