| 3,5-二溴水杨醛水杨酰腙及金属M(M=Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ))配合物的合成与结构特征 |
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| 引用本文： | 吴宇,程翠霞,施少敏,加兵,胡宗球.3,5-二溴水杨醛水杨酰腙及金属M(M=Zn(Ⅱ)、Cu(Ⅱ)、Ni(Ⅱ))配合物的合成与结构特征[J].华中师范大学学报(自然科学版),2006,40(1):55-57. |
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| 作者姓名： | 吴宇 程翠霞 施少敏 加兵 胡宗球 |
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| 作者单位： | 华中师范大学,化学学院,武汉,430079 |
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| 摘 要： | 合成了3，5-二溴水杨醛水杨酰腙配体及其金属锌、铜、镍的配合物，培养出锌配合物晶体．通过测定配体和配合物的元素分析、红外光谱、电子光谱、摩尔电导、质谱和核磁共振及锌配合物晶体，确定为六配位化合物，其中溶剂分子参与了配位．并对锌配合物晶体的结构特征进行了分析．
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| 关 键 词： | 3 5-二溴水杨醛水杨酰腙 配合物 晶体结构 |
| 文章编号： | 1000-1190（2006）01-0055-03 |
| 收稿时间： | 2005-05-13 |
| 修稿时间： | 2005-05-13 |
Synthesis and structure properties of 3,5-dibromosalicylaldehyde salicylhydrazone and its metal complexes |
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| WU Yu,CHENG Cui-xia,SHI Shao-min,JIA Bing,HU Zong-qiu.Synthesis and structure properties of 3,5-dibromosalicylaldehyde salicylhydrazone and its metal complexes[J].Journal of Central China Normal University(Natural Sciences),2006,40(1):55-57. |
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| Authors: | WU Yu CHENG Cui-xia SHI Shao-min JIA Bing HU Zong-qiu |
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| Institution: | College of Chemistry, Central China Normal University, Wuhan 430079 |
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| Abstract: | The complexes of copper, zinc, nickel with 3,5-dibromosalicylaldehyde salicylhydrazone were synthesized in DMF and pyridine. The crystal of zinc complex with 3,5-dibromosalicylaldehyde salicylhydrazone was obtained. Their six-coordinated forms which included solvent molecules were confirmed by their elemental analysis, IR, UV, conductivity, electronic spectra, MS, 1H NMR and X-ray diffraction. The crystal structure of zinc complex was analyzed. |
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| Keywords: | 3 5-dibromosalicylaldehyde salicylhydrazone complexes crystal structure |
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