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煤与氧反应动力学数学模型及其求解
引用本文:余明高,王清安,范维澄,廖光煊.煤与氧反应动力学数学模型及其求解[J].湖南科技大学学报(自然科学版),2001,16(3):20-23.
作者姓名:余明高  王清安  范维澄  廖光煊
作者单位:中国科学技术大学
基金项目:煤炭科学基金资助项目(97安21107)
摘    要:研究煤自然发火的核心是研究煤自然发火机理.在煤氧复合作用学说基础上,建立了煤与氧反应动力学数学模型,通过该模型并结合实验数据,能计算出煤在氧化过程中的一系列动力学参数.计算实例表明,该模型所计算的各项参数能充分反映煤与氧反应的特征,为探索煤自然发火机理以及如何评价煤自然发火危险性提供了一条可行的技术途径.表3,参6.

关 键 词:煤氧复合作用  动力学参数  化学吸附  吸氧速度  吸附表面
文章编号:1000-9930(2001)03-0020-04
修稿时间:2001年1月9日

The dynamics mathematical model of reaction between coal and oxygen and its calculating method
YU Ming gao,WANG Qing an,FAN Wei cheng,LIAO Guang xuan.The dynamics mathematical model of reaction between coal and oxygen and its calculating method[J].Journal of Hunan University of Science & Technology(Natural Science Editon),2001,16(3):20-23.
Authors:YU Ming gao  WANG Qing an  FAN Wei cheng  LIAO Guang xuan
Abstract:The kernel of studying on coal spontaneous combustion is researching its spontaneous combustion mechanism.Based on coal oxygen complex action theory,this paper has set up the dynamics mathematical model of reaction between coal and oxygen. By means of the mathematical model,and combined with the experimental datum,a series of dynamics parameters of reaction between coal and oxygen in the progress of temperature rising can be calculated.From the calculating example, it indicated that the calculating parameters can entirely reflect the features of reaction between coal and oxygen. This method provides a feasible technical approach to explore the mechanism of coal spontaneous combustion and how to estimate the fatalness of coal spontaneous combustion. 3tabs.,6refs.
Keywords:coal oxygen complex action  dynamics parameters  chemical adsorption  rate of oxygen  adsorption  adsorption surface
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