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新型分子筛CeAPO-5的合成及表征
引用本文:张岩.新型分子筛CeAPO-5的合成及表征[J].科学技术与工程,2011,11(6).
作者姓名:张岩
作者单位:榆林学院化学与化工学院,榆林,719000
摘    要:采用水热合成法,以拟薄水铝石,正磷酸,碳酸铈,水为原料,三乙胺为模板剂合成了新型CeAPO-5分子筛。利用XRD、FT-IR、SEM和BET等手段对它的晶体结构、表面形貌做了系统的表征。结果表明CeAPO-5分子筛具有AlPO-5分子筛的晶体结构。Ce(III)的引入并没有改变分子筛的骨架结构。但会增加新型分子筛CeAOP-5分子筛的比表面积。

关 键 词:水热合成  磷酸盐  
收稿时间:11/4/2010 5:30:00 PM
修稿时间:2010/12/21 0:00:00

Synthesis and characterization of cerium aluminophosphate molecular sieve(CeAPO-5)
zhangyan.Synthesis and characterization of cerium aluminophosphate molecular sieve(CeAPO-5)[J].Science Technology and Engineering,2011,11(6).
Authors:zhangyan
Institution:ZHANG Yan,GAO Ping-qiang(School of Chemistry and Chemical Engineering,Yulin college,Yulin 719000,P.R.China)
Abstract:Cerium (III) aluminophosphate molecular sieve has been synthesized starting from pseudo-boehmite , phosphoric acid, cerium carbonate, and water, in the presence of a triethylamine organic template. Based on the synthesized material, many of characterization were carried out by XRD, FT-IR, SEM, BET methods. It shows that the material has a tetrahedral framework of APO4] and PO4].The obtained structure was similar to that of AlPO-5. The incorporation of Ce (III) ions into the framework did not change the AlPO-5 structure, but did, however, increase the surface area.
Keywords:Hydrothermal synthesis  aluminophosphate  cerium
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