| ZnO对C02加氢制甲醇用Cu0-Zr02 催化剂性能的影响 |
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| 引用本文： | 郭晓明,毛东森,卢冠忠,王嵩.ZnO对C02加氢制甲醇用Cu0-Zr02 催化剂性能的影响[J].上海应用技术学院学报,2013,13(4):259-262. |
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| 作者姓名： | 郭晓明 毛东森 卢冠忠 王嵩 |
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| 作者单位： | [1]上海应用技术学院化学与环境工程学院,上海201418 [2]华东理工大学工业催化研究所,上海200237 |
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| 基金项目： | 上海应用技术学院科技发展基金资助项目（KJ2010-05） |
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| 摘 要： | 在CuO—ZrO2催化剂中引入ZnO2考察了ZnO对CuO-ZrOz物化性能及催化CO2加氢合成甲醇性能的影响，优化了CuO—ZnO—ZrO2催化剂的Zn／Zr比。结果表明，适量ZnO的添加增加了催化剂中铜的比表面积，显著提高了催化剂表面的碱性位数目，从而有利于H2的吸附解离和C02的吸附。ZnO的加入提高了催化剂的催化活性和甲醇选择性，当Zn／Zr比为2：3时，催化活性最高。
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| 关 键 词： | ZnO CuO—ZrO2 二氧化碳加氢 甲醇 |
The Influence of ZnO on the Performance of CuO-Zr02 for Methanol Synthesis via C02 Hydrogenation |
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| GUO Xiao-ming,MAO Dong-sen,LU Guan-zhong and WANG Song.The Influence of ZnO on the Performance of CuO-Zr02 for Methanol Synthesis via C02 Hydrogenation[J].Journal of Shanghai Institute of Technology: Natural Science,2013,13(4):259-262. |
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| Authors: | GUO Xiao-ming MAO Dong-sen LU Guan-zhong and WANG Song |
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| Institution: | 1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China; 2. Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China) |
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| Abstract: | The effects of ZnO on the physicochemical properties and the catalytic performance of CuO-ZrO2 for the hydrogenation of CO2 to methanol were investigated. The results showed that the specific surface area of metallic copper in the catalyst, which was favorable for the adsorption and dissociation of H2, increased with the addition of an appropriate amount of ZnO. Moreover, the amount of basic sites on the catalyst surface was greatly enhanced by the presence of ZnO, resulting in an increase of the adsorbed O32. The highest activity could be obtained when the ratio of Zn/Zr was 2：3 in the CuO-ZnO-ZrO2 catalyst. |
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| Keywords: | ZnO CuO-ZrO2 CO2 hydrogenation methanol |
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