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均匀设计在UHMWPE纺丝拉伸工艺优化中的应用
引用本文:郑华强,郑晗,王新威.均匀设计在UHMWPE纺丝拉伸工艺优化中的应用[J].上海应用技术学院学报,2017,17(4):295-299.
作者姓名:郑华强  郑晗  王新威
作者单位:聚烯烃催化技术与高性能材料国家重点实验室, 上海 200062;上海化工研究院, 上海 200062,聚烯烃催化技术与高性能材料国家重点实验室, 上海 200062;上海市聚烯烃催化技术重点实验室, 上海 200062;上海化工研究院, 上海 200062,聚烯烃催化技术与高性能材料国家重点实验室, 上海 200062;上海市聚烯烃催化技术重点实验室, 上海 200062;上海化工研究院, 上海 200062
基金项目:上海市科委基金项目(15DZ1203200)资助
摘    要:以UHMWPE干法初生丝为原料进行三级连续热拉伸。参考均匀设计研究了拉伸过程中的各级温度、拉伸比、进丝速度共7个影响因素对产品丝的强度影响,利用二次多项式逐步回归优化了工艺条件,并用留一法计算PRESS对模型的预报功能进行验证。工艺优化后的纤维平均强度可达33.47cN/dtex,达到了优化的目的。

关 键 词:超高分子量聚乙烯    纤维    干法纺丝    连续拉伸    均匀设计
收稿时间:2017/3/14 0:00:00

Application of Uniform Design in the Optimization of UHMWPE Fibers Drawing Process
ZHENG Huaqiang,ZHENG Han and WANG Xinwei.Application of Uniform Design in the Optimization of UHMWPE Fibers Drawing Process[J].Journal of Shanghai Institute of Technology: Natural Science,2017,17(4):295-299.
Authors:ZHENG Huaqiang  ZHENG Han and WANG Xinwei
Institution:State Key Laboratory of Polyolefins and Catalysis, Shanghai 200062, China;Shanghai Research Institute of Chemical Industry, Shanghai 200062, China,State Key Laboratory of Polyolefins and Catalysis, Shanghai 200062, China;Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai 200062, China;Shanghai Research Institute of Chemical Industry, Shanghai 200062, China and State Key Laboratory of Polyolefins and Catalysis, Shanghai 200062, China;Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai 200062, China;Shanghai Research Institute of Chemical Industry, Shanghai 200062, China
Abstract:A three-stage continuous hot drawing experiment was carried out on as-spun samples whit fabricated by dry spinning method. The influence of seven factors in drawing process on the strength of fibers was studied by using the uniform design and quadratic polynomial stepwise regression method, and cross-validation models was used to calculate the predicted residual error sum of squares (PRESS) statistic. The average fiber strength of the optimized process could reach 33.47 cN/dtex.
Keywords:ultra high molecular weight polyethylene
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