| PEG在ZrO2前驱体表面的吸附及改性作用 |
| |
| 引用本文： | 徐明霞,方洞浦.PEG在ZrO2前驱体表面的吸附及改性作用[J].天津大学学报(自然科学与工程技术版),1994,27(2):172-178. |
| |
| 作者姓名： | 徐明霞 方洞浦 |
| |
| 摘 要： | 以粘度法测定了高分子型表面活性剂聚乙二醇（ＰＥＧ）在ＺｒＯ２前驱体表面上的吸附量和水洗后的残留量，结合粉体改性效果和ＩＲ，ＸＰＳ技术对前驱体表面－ＯＨ，ＰＥＧ在加热过程中分解脱除情况的测定结果，分析了ＰＥＧ大分子在前驱体表面上的吸附状态及其对前驱体表面性能的影响，有助于了解ＰＥＧ大分子对湿化学法制备超细ＺｒＯ２陶瓷粉体的改性作用，为进一步优化表面改性工艺条件提供实能依据。
|
| 关 键 词： | 二氧化锆 前驱体 表面活性剂 |
ADSORPTION AND MODIFICATION OF MACROMOLECULAR PEG ON THE ZrO_2 PRECURSOR |
| |
| Xu Mingxia, Fang Dongpu, Guo Ruisong, Zhu Guanhua Xu Hong, Yang Zhengfang..ADSORPTION AND MODIFICATION OF MACROMOLECULAR PEG ON THE ZrO_2 PRECURSOR[J].Journal of Tianjin University(Science and Technology),1994,27(2):172-178. |
| |
| Authors: | Xu Mingxia Fang Dongpu Guo Ruisong Zhu Guanhua Xu Hong Yang Zhengfang |
| |
| Institution: | Dept. of Materials Science and Engineering |
| |
| Abstract: | he adsorbent and the residual amount of a kind of polymeric surfactant,PEG, on the surface of a ZrO2 precursor are quantitatively measured by viscosimetry. Combined this with the effects of improving powder and the results of IR and XPS showing the changes of -OH and PEG on the precursor surface during temperature rise, the adsorption of macromolecular PEG on the precursor surface and the influence of PEG on the properties of the precursor surface are discussed. These results provide an experimental basis for better understanding the surface modification principle of ultrafifle powders and for further optimizing technical conditions of surface modification. |
| |
| Keywords: | ultrafine powder ZrO_2 precursor surfactant surface modification |
| 本文献已被 CNKI 维普 等数据库收录！ |
