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Cu-TiO2纳米复合镀层的腐蚀和光催化性能
引用本文:贺春林,李海松,张金林,杨雪飞,王建明,才庆魁.Cu-TiO2纳米复合镀层的腐蚀和光催化性能[J].沈阳大学学报,2012,24(2):40-44.
作者姓名:贺春林  李海松  张金林  杨雪飞  王建明  才庆魁
作者单位:沈阳大学辽宁省先进材料制备技术重点实验室,辽宁沈阳,110044
基金项目:国家自然科学基金资助项目,教育部留学回国人员科研启动基金
摘    要:采用纳米复合镀技术在铝表面制备了Cu-TiO2纳米复合镀层,利用扫描电镜、电化学测试系统、分光光度计对其形貌、腐蚀和光催化性能进行了研究.结果表明,TiO2纳米颗粒在铜基复合膜层中的分散均匀;TiO2颗粒的加入可使Cu-TiO2纳米复合镀层腐蚀电位明显增加,膜层的耐蚀性提高;在紫外光照射下,复合镀层对甲基橙溶液有明显的光催化降解作用,且这种作用随时间延长而有所增大.

关 键 词:Cu  TiO2纳米颗粒  纳米复合材料  耐蚀性  光催化

Corrosion Behavior and Photocatalytic Performance of Cu-TiO2 Nanocomposite Coating
HE Chunlin,LI Haisong,ZHANG Jinlin,YANG Xuefei,WANG Jianming,CAI Qingkui.Corrosion Behavior and Photocatalytic Performance of Cu-TiO2 Nanocomposite Coating[J].Journal of Shenyang University,2012,24(2):40-44.
Authors:HE Chunlin  LI Haisong  ZHANG Jinlin  YANG Xuefei  WANG Jianming  CAI Qingkui
Institution:(Liaoning Provincial Key Laboratory of Advanced Materials, Shenyang University, Shenyang 110044, China)
Abstract:The Cu-TiO2 nanocomposite coating was prepared by nanocomposite plating memoa, and its microstructure, corrosion resistance and photocatalytic property were investigated with SEM/ EDX, electrochemical technology and UV-Vis absorption spectrum. The results show that TiO2 nanoparticles are uniformly distributed in the Cu matrix coating. The electrochemical results show that the Cu-TiO2 nanocomposite coating exhibits much higher corrosion potential and better corrosion resistance than those o{ Cu plating coating and Al substrate in 3.5 % NaCI solution. Under ultraviolet radiation, Cu-TiO2 nanocomposite coating exhibits efficiently photocatalytic degradation effect on methyl orange, and this effect can be enhanced as the degradation time is prolonged.
Keywords:Cul TiO2 nanoparticle nanocomposite corrosion resistance photocatalytic property
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