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有机改性凹凸棒石吸附活性艳蓝KN-R的热力学研究
引用本文:张波,彭书传.有机改性凹凸棒石吸附活性艳蓝KN-R的热力学研究[J].安徽大学学报(自然科学版),2009,33(4).
作者姓名:张波  彭书传
作者单位:1. 安徽职业技术学院,化学工程系,安徽,合肥,230051
2. 合肥工业大学,资源与环境学院,安徽,合肥,230009
基金项目:国家自然科学基金资助项目(40672027)
摘    要:利用静态吸附实验方法,研究了有机改性凹凸棒石吸附活性艳蓝KN-R的热力学性质.在实验范围内,有机改性凹凸棒石对水中活性艳蓝KN-R的吸附平衡数据符合Freund lich吸附等温方程.研究结果表明:吸附焓变为正值,表明该吸附过程是吸热的,升高温度有利于吸附.吸附自由能为负值,表明该过程是常温下可以自发进行的.

关 键 词:有机改性  凹凸棒  吸附  活性艳蓝KN-R  热力学

The study of thermodynamics of adsorption of reactive brilliant blue KN-R onto organic modified palygorskite
ZHANG Bo,PENG Shu-chuan.The study of thermodynamics of adsorption of reactive brilliant blue KN-R onto organic modified palygorskite[J].Journal of Anhui University(Natural Sciences),2009,33(4).
Authors:ZHANG Bo  PENG Shu-chuan
Institution:1.Department of Chemical Engineering;Anhui Vocational and Technical College;Hefei 230051;China;2.School of Resources and Environmental Engineering;Hefei University of Technology;Hefei 230009;China
Abstract:By using passive absorption method,it was studied that the thermodynamic properties of the absorption of organic modified palygorskite on reactive brilliant blue KN-R.Equilibrium data for the adsorption of KN-R onto organic modified palygorskite within the rang were obtained and correlated with Freundlich-type isotherm equations.The results indicated that the absorption process was endothermic,and the temperature is conducive to increased absorption.Free energy absorption was negative,indicated that the pro...
Keywords:organic modification  palygorskite  absorption  reactive brilliant blue KN-R  thermodynamic  
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