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MMA-DVB大孔树脂对二氯苯酚等的吸附性能
引用本文:高俊刚,崔岳,王红,张顺霞.MMA-DVB大孔树脂对二氯苯酚等的吸附性能[J].河北大学学报(自然科学版),2004,24(4):377-381.
作者姓名:高俊刚  崔岳  王红  张顺霞
作者单位:1. 河北大学,化学与环境科学学院,河北,保定,071002
2. 保定石油化工二厂,河北,保定,071000
摘    要:用悬浮聚合的方法,以乙酸乙酯和石油醚作致孔剂,合成了聚甲基丙烯酸甲酯(MMA)_二乙烯基苯(DVB)大孔吸附树脂.系统研究和比较了此种吸附树脂对苯酚、间甲基苯酚、邻硝基苯酚和2,4_二氯苯酚的静态和动态吸附性能,并初步探讨了酚结构对吸附性能的影响.实验证明MMA_DVB大孔吸附树脂对2,4_二氯苯酚的动态吸附量达191.54mg/g,明显高于其他3种酚,具有良好的选择性.乙醇水溶液是适宜的洗脱剂.

关 键 词:大孔树脂  废水处理  2  4-二氯苯酚  吸附
文章编号:1000-1565(2004)04-0377-05
修稿时间:2003年9月7日

Adsorption Ability of PMMA/DVB Absorbent for 2,4-Dichlorophenol
GAO Jun-gang,CUI Yue,WANG Hong,ZHANG Shun-xia.Adsorption Ability of PMMA/DVB Absorbent for 2,4-Dichlorophenol[J].Journal of Hebei University (Natural Science Edition),2004,24(4):377-381.
Authors:GAO Jun-gang  CUI Yue  WANG Hong  ZHANG Shun-xia
Institution:GAO Jun-gang~1,CUI Yue~1,WANG Hong~2,ZHANG Shun-xia~1
Abstract:The macroporous methylmethacrylate-divinylbenzene copolymer absorbent was synthesized with petroleum ether and ethyl acetalte as porogenic agent by suspension copolymerization. Adsorption ability of this absorbent for 2,4-dichlorophenol, phenol, m-cresol and o-nitrophenol were investigated.The effects of adsorption time, phenol concentrations and structure of phenols on adsorption quantity were investigated. The dynamic adsorption quantity for 2,4-dichlorophenol is 191.54 mg/g, which is obviously larger than those of the other three kinds of phenols. Ethanol solution is a kind of efficient eluent.
Keywords:macroporous absorbent  wastewater treatment  2  4-dichlorophenol  adsorption
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