| 橡胶单体热解动力学过程及模型 |
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| 引用本文： | 周浩生,周琥,陆继东.橡胶单体热解动力学过程及模型[J].华中科技大学学报(自然科学版),2001,29(Z1):11-13. |
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| 作者姓名： | 周浩生 周琥 陆继东 |
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| 作者单位： | 华中科技大学 |
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| 摘 要： | 应用热综合分析仪(TG/FTIR)研究了橡胶的三种单体(天然胶Nr,丁苯胶SBr和顺丁胶Br)的热解过程.TG/DTG曲线表明单体的热解可分为2～3个阶段,其中SBr的初始热解温度和Nr完全热解的温度最低;升温速率改变单体热解速率最大值和其对应的温度.三种单体热解析出的气体组分复杂.最后,计算了三种单体热解的动力学参数.
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| 关 键 词： | 橡胶 热解 动力学模型 |
| 文章编号： | 1000-8616(2001)1-0011-03 |
| 修稿时间： | 1999年11月19 |
Kinetic Model for the Pyrolysis of Tyre Components |
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| Zhou Haosheng Zhou Hu Lu Jidong State Key Lab. of Coal Combustion,HUST Wuhan ,China..Kinetic Model for the Pyrolysis of Tyre Components[J].JOURNAL OF HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY.NATURE SCIENCE,2001,29(Z1):11-13. |
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| Authors: | Zhou Haosheng Zhou Hu Lu Jidong State Key Lab of Coal Combustion HUST Wuhan China |
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| Institution: | Zhou Haosheng Zhou Hu Lu Jidong State Key Lab. of Coal Combustion,HUST Wuhan 430074,China. |
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| Abstract: | The tyre styrene butadine rubber (Sbr), natural rubber(Nr) and polybutadine rubber(Br) which are the major rubber components are pyrolysed in a TGA/FTIR analyzer under nitrogen at various heting rates. TG/DTG curves demonstrate two to three areas of weight loss which represent a lower and a higher temperature of decomposition. The lowest temperature of initial decomposition and that of full decomposition are Sbr and Nr respectively. The heating rates shift the maximum thermal degradation rate and its corresponding temperature. The evolution of gases during the pyrolysis is analyzed and the kinetic parameters are calculated. |
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| Keywords: | rubber pyrolysis kinetic model |
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