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脉冲电晕放电脱硝中N_2O生成的研究
引用本文:冯波,林志杰,袁建伟,刘德昌.脉冲电晕放电脱硝中N_2O生成的研究[J].华中科技大学学报(自然科学版),1994(3).
作者姓名:冯波  林志杰  袁建伟  刘德昌
作者单位:华中理工大学煤燃烧国家重点实验室
基金项目:国家自然科学基金,国家攀登计划资助项目
摘    要:脉冲电晕放电是一种能同时脱除烟气中SO2,NOx和飞灰颗粒的新方法。然而在一个电晕放电试验装置上的试验首次发现,在脱除NOx的同时产生了一定量的N_O,而且随着电压和停留时间及NOx初始浓度的增大,N_2O量也增大。试验还发现,电晕放电对N_2O无分解作用,空气中的氮气在电晕中不生成N2O,脱硫及喷氮脱硫不生成N2O,SO2和NH3对N_2O的生成无影响。讨论了脉冲电晕放电脱硝中N2O生成的机理。

关 键 词:煤燃烧  N_2O的生成  脱除NOx  脉冲电晕

Nitrous Oxide Formation during NO_x Removal by Pulsed Corona Discharge
Feng BoDept,of Power Engin.,H.U.S.T.,Wuhan,China. Lin Zhijie ,Yuan Jianwei ,Liu Dechang.Nitrous Oxide Formation during NO_x Removal by Pulsed Corona Discharge[J].JOURNAL OF HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY.NATURE SCIENCE,1994(3).
Authors:Feng BoDept  of Power Engin  HUST  Wuhan    China Lin Zhijie  Yuan Jianwei  Liu Dechang
Institution:Feng BoDept,of Power Engin.,H.U.S.T.,Wuhan,430074,China. Lin Zhijie ,Yuan Jianwei ,Liu Dechang
Abstract:A pulse-energized electron reactor utilizing pulsed streamer corona has been developedfor simultaneous removal of SO2 ,NO_x and particles from effluent gases, However,nitrousoxide formation was observed during NO_x removal. The main parameters that determine theamount of N2O formation in the reactor are the voltage, residence time and initial NOx con-centration. N2O increases with the increase of voltage, residence time and initial NOx concen-tration, Pulsed corona discharge showed no effect on N2O decomposition. No N2O formationwas detected in the reactor from air,air/SO2 mixture and air/SO2/NH3 mixed gases.The ex-perimental results suggest that N2O comes only from the oxidation of NO_x and SO2 has littlecatalyzing effect on the reaction.
Keywords:coal combustion  nitrous oxide formation  NO_x removal  pulsed corona
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