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Ce—Y—TZP陶瓷中的马氏体相变与形状记忆效应
引用本文:张玉龙,金学军,徐祖耀,张玉峰,施剑林.Ce—Y—TZP陶瓷中的马氏体相变与形状记忆效应[J].上海交通大学学报,2001,35(3):385-388.
作者姓名:张玉龙  金学军  徐祖耀  张玉峰  施剑林
作者单位:1. 上海交通大学材料科学与工程学院,
2. 中国科学院上海硅酸盐研究所,
基金项目:美国Emerson电气公司资助项目
摘    要:用共沉淀法制备了8mol?O2-0.25mol%Y2O3-ZrO2(8Ce-0.25Y-TZP)、8Ce-0.50Y-TZP和8Ce-0.75Y-TZP3种成分的超细粉,于1500℃分别烧结2、3、6h成形。8Ce-0.25Y-TZP的马氏体相变开始温度Ms在室温以上,室温下基本上不具有形状记忆效应;8Ce-0.50Y-TZP的形状记忆效应最佳,其中烧结6h的试样最大可恢复应变为1.18%;8Ce-0.75Y-TZP的形状记忆效应较差。Ms与材料的强度密切相关,晶粒大小和密度等也有影响。

关 键 词:形状记忆效应  马氏体相变  陶瓷  四方氧化锆多晶      TZP  强度
文章编号:1006-2467(2001)03-0385-04
修稿时间:2000年6月6日

Martensitic Transformation and Shape Memory Effect in Ce-Y-TZP Ceramics
ZHANG Yu-long,JIN Xue-jun,XU Zu-yao,ZHANG Yu-feng,SHI Jian-lin.Martensitic Transformation and Shape Memory Effect in Ce-Y-TZP Ceramics[J].Journal of Shanghai Jiaotong University,2001,35(3):385-388.
Authors:ZHANG Yu-long  JIN Xue-jun  XU Zu-yao  ZHANG Yu-feng  SHI Jian-lin
Institution:ZHANG Yu long 1,JIN Xue jun 1,XU Zu yao
Abstract:Superfine powders with compositions 8 mol%CeO2-0. 25 mol%Y2O3-ZrO2 (8Ce-0. 25Y-TZP), 8Ce-0.50Y-TZP and 8Ce-0. 75Y-TZP were prepared by the coprecipitation method and sintered at 1 500℃ for 2,3 and 6 hours respectively. 8Ce-0. 25Y-TZP having martensitic transformation temperatures (Ms) above room temperature does not exhibit shape memory effect (SME) at ambient temperature. 8Ce0.50Y-TZP shows the best SME, and the largest recoverable strain of 1.18% in the specimens sintered at 1 500℃ for 6 hours was attained. The Ms of the material is closely related to its strength, and other factors such as grain size and density also have influence on the Ms.
Keywords:shape memory effect  martensitic transformation  ceramics
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