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交联杂萘聚醚酮质子交换膜的合成及性能研究
引用本文:丁富传,陈清松,王拴紧,肖敏,孟跃中.交联杂萘聚醚酮质子交换膜的合成及性能研究[J].中山大学学报(自然科学版),2009,48(Z2).
作者姓名:丁富传  陈清松  王拴紧  肖敏  孟跃中
作者单位:1. 中山大学理工学院光电子国家重点实验室,广东,广州,510275;福建师范大学化学与材料科学学院,福建,福州,350007
2. 福建师范大学化学与材料科学学院,福建,福州,350007
3. 中山大学理工学院光电子国家重点实验室,广东,广州,510275
基金项目:国家高技术研究发展计划(863计划) 
摘    要:将含丙烯基侧链的磺化杂萘聚醚酮与交联剂双马来酰亚胺(BMI)溶液共混成膜,再加热使双键交联,报道了一种制备含丙烯基不饱和基团的交联磺化杂萘聚醚酮质子交换膜的新方法,比较了交联前后膜的各项性能.

关 键 词:交联  导质子率  磺化  

Proton Exchange Memebrane for PEM Fuel Cell Application Based on Cross-linked Sulfonated Poly (phathalazinone ether ketone)s
DING Fuchuan,CHEN Qingsong,WANG Shuanjin,XIAO Min,MENG Yuezhong.Proton Exchange Memebrane for PEM Fuel Cell Application Based on Cross-linked Sulfonated Poly (phathalazinone ether ketone)s[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2009,48(Z2).
Authors:DING Fuchuan  CHEN Qingsong  WANG Shuanjin  XIAO Min  MENG Yuezhong
Abstract:A new method for the preparation of proton exchange membranes (PEMs), based on cross-linked sulfonated Poly (phathalazinone ether ketone)s by thermally curing using BMI as cross-linking agent is reported. The comprehensive properties of the virgin and the cross-linked membranes were compared accordingly. The results showed that the cross-linked membranes revealed the better mechanical, oxidative and dimensional stabilities together with no obvious infection on proton conductivity.
Keywords:cross-linking  proton conductivity  sulfonation  membrane
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