| MCM—41中孔分子筛的全微波辐射快速合成 |
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| 引用本文： | 张迈生,陈接胜.MCM—41中孔分子筛的全微波辐射快速合成[J].中山大学学报(自然科学版),1998,37(2):128-130. |
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| 作者姓名： | 张迈生 陈接胜 |
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| 作者单位： | 中山大学化学与化学工程学院，吉林大学化学系 |
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| 基金项目： | 吉林大学无机合成与制备化学开放研究实验室基金 |
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| 摘 要： | 采用正硅酸乙酯（ＴＥＯＳ）作硅源，十六烷基溴化铵（ＣＴＡＢｒ）作为模板剂，首次通过全微波辐射法合成了ＭＣＭ－４１中孔分子筛，用ＸＲＤ，ＴＧ，ＩＲ和ＳＥＭ等实验技术进行了表征．结果表明，此法合成时间短，晶化只需１０～１５ｍｉｎ，焙烧脱模也仅需１ｈ左右．本实验条件下，所得分子筛晶粒分布均匀，晶形以球状为主，晶粒大小约为１０μｍ．全微波辐射合成法，具有工艺简单，操作方便，省电节能，产品收得率高等特点．它可能为ＭＣＭ－４１中孔分子筛的快速合成，探索出一条新的途径．
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| 关 键 词： | MCM－41中孔分子筛，微波辐射，合成 |
Synthesis of MCM 41 Mesoporous Molecular Sieve by Microwave Radiation Method |
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| Zhang MaishengSchool of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou ,China Li Li Yang Yansheng Chen Jiesheng Xu Ruren.Synthesis of MCM 41 Mesoporous Molecular Sieve by Microwave Radiation Method[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,1998,37(2):128-130. |
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| Authors: | Zhang MaishengSchool of Chemistry and Chemical Engineering Zhongshan University Guangzhou China Li Li Yang Yansheng Chen Jiesheng Xu Ruren |
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| Institution: | Zhang MaishengSchool of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou 510275,China Li Li Yang Yansheng Chen Jiesheng Xu Ruren |
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| Abstract: | In this investigation, MCM 41 mesoporous molecular sieve was firstly synthesized with tetraethyl orthosilicate(TEOS) as the source of sillica and cetyltrimethylammonium bromide(CTABr) as the template by microwave radiation method (including the processess of crystallization and de template).It was characterized by XRD,TG,IR and SEM. |
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| Keywords: | MCM 41 mesoporous molecular sieve microwave radiation synthesis |
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