含手性原子的希夫碱系化合物的合成及SHG效应 |
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引用本文: | 赵晓明,陈兴.含手性原子的希夫碱系化合物的合成及SHG效应[J].大连理工大学学报,1997,37(5):538-541. |
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作者姓名: | 赵晓明 陈兴 |
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作者单位: | 大连理工大学精细化工国家重点实验室 |
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摘 要: | 合成了含手性原子的中间体及六个希夫碱,测试工了旋光度和吸收光谱,含手性原子的化合物均有旋光值。所合成的样品最大吸收波长λmax为329.3-372.8nm。
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关 键 词: | 手性原子 席夫碱 SHG效应 非线性光学性能 |
Synthesis and SHG activity of chiral Schiff base derivatives |
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Abstract: | Six kinds of chiral Schiff bases have been synthesized by the condensation of chiral aromatic amine and aromatic aldehyde. The absorption curves of UV visible have been measured and it is found that their maximum absorption wavelengths are all in the ultraviolet region. The absorption wavelength of Schiff bases compounds causes red shift with the weak electron donor group on the aromatic amine ring and the electron acceptor group on the aromatic aldehyde ring. The second harmornic generation of synthesized compounds have been measured by the powder method and it is found that two samples possess SHG activity. |
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Keywords: | non linear materials/optical effects chiral atom Schiff base the second harmonic generation |
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