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四氯化碳质谱研究
引用本文:汪生德,曹正品.四氯化碳质谱研究[J].西华师范大学学报(哲学社会科学版),1988(3).
作者姓名:汪生德  曹正品
作者单位:南充师范学院,西南石油学院
摘    要:用四极质谱法测CCl_4的质谱。根据所测四氯化碳各种碎片离子的同位素分布比,计算出氯元素原子的平均原子量及CCl_4的平均分子量。结果表明:质谱法测得的CCl_4分子量比冻点下降法、蒸气密度法、……等所测CCl_4分子量的偏差小。

关 键 词:质谱法  四氯化碳  同位素  相对丰度  分子量

A STUDY ON THE MASS SPECTRUM OF CARBON TETRACHLORIDE
Wang Shengde Nanchong Teachers'''' College Chao Zhengpin Southwest Institute Petroleum.A STUDY ON THE MASS SPECTRUM OF CARBON TETRACHLORIDE[J].Journal of China West Normal University:Natural Science Edition,1988(3).
Authors:Wang Shengde Nanchong Teachers' College Chao Zhengpin Southwest Institute Petroleum
Institution:Wang Shengde Nanchong Teachers' College Chao Zhengpin Southwest Institute Petroleum
Abstract:The mass spectrum of ccl_4(carbon tetrachloride)was determined with quadrupole mass spectrometry, Based on the isotope distribution ratio of different fragments of ccl, the paper calculated the average atomic weight of chloride element and the average molecular weight of ccl~4. The experiment showed that the molecular weight of ccl_4 determined with mass spectrometry conforms to the standard value and its deviation is less than that of cryoscopic method, vapor densitymethoq etc.
Keywords:mass spectrometry  carbon tetrachloride  isotope  relative abundances  molecular weight
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