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钨酸铜的生成及其氢还原过程的研究
引用本文:吴恩熙,钱崇梁,邹志强,张玉华.钨酸铜的生成及其氢还原过程的研究[J].中南大学学报(自然科学版),1993(1).
作者姓名:吴恩熙  钱崇梁  邹志强  张玉华
作者单位:粉末冶金研究所,粉末冶金研究所,粉末冶金研究所,粉末冶金研究所
摘    要:本文提出一种生产微细钨铜复合粉的方法。将WO_3(或蓝钨)和CuO均匀混合,在空气中焙烧生成CuWO_4,再在氢气中还原,就能制得微细钨铜复合粉,其钨、铜两相分布均匀,钨颗粒细小且分布狭窄。本文详细地研究了钨酸铜的生成及其氢还原过程,与WO_3相比,发现两者的还原相变过程及动力学过程有某些差异。

关 键 词:钨酸铜  复合粉  X射线衍射  相变

A STUDY ON FORMATION AND H_2-REDUCTION OF COPPER TUNGSTATE
Wu Enxi,Qian Chongliang,Zou Zhiqiang,Zhang Yuhua Powder Metallurgy Research Institute.A STUDY ON FORMATION AND H_2-REDUCTION OF COPPER TUNGSTATE[J].Journal of Central South University:Science and Technology,1993(1).
Authors:Wu Enxi  Qian Chongliang  Zou Zhiqiang  Zhang Yuhua Powder Metallurgy Research Institute
Institution:Wu Enxi;Qian Chongliang;Zou Zhiqiang;Zhang Yuhua Powder Metallurgy Research Institute
Abstract:This study deals with a new method for the preparation of fine tungsten-copper com-posite powder. First, the WO_3 or blue tungsten oxide powder was mixed uniformly with CuOpowder. Then, the mixture was calcined in air and became CuWO_4 powder. Finally, thepowder was reduced with H_2. The tungten-copper composite powder with very fine tungstenparticles and well-sized distribution can be prepared. The detail of the formation and H_2-re-duction characteristics of the copper tungstate are given in this paper. The difference of thereduction characteristics of the copper tungstate and the WO_3 is also presented.
Keywords:copper tungstate  composite powder  phase transformation  X-ray diffraction
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