| 氨基脲桥联杯[4]芳烃衍生物的合成及性能研究 |
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| 引用本文： | 郑林禄,杨发福,刘朝晖.氨基脲桥联杯[4]芳烃衍生物的合成及性能研究[J].齐齐哈尔大学学报(自然科学版),2013(1):52-55. |
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| 作者姓名： | 郑林禄 杨发福 刘朝晖 |
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| 作者单位： | 宁德师范学院化学系;福建师范大学化学与材料学院 |
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| 基金项目： | 福建省教育厅科技项目(JB10189);“服务海西建设”项目(2011H209) |
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| 摘 要： | 设计并合成了下沿含缩氨脲基和席夫碱基的新型桥联杯4]芳烃衍生物,经1H NMR、MS和元素分析等表征确证其结构;测定了新型桥联杯4]芳烃衍生物对金属阳离子和氨基酸分子的两相萃取性能,结果表明新型主体分子通过多官能团的协同作用具有较好的配位性能。
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| 关 键 词： | 杯[4]芳烃 氨基脲 桥联 配位性能 |
Synthesis and properties of semicarbazide-bridged calix[4]arene derivative |
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| ZHENG Lin-lu,YANG Fa-fu,LIU Chao-hui.Synthesis and properties of semicarbazide-bridged calix[4]arene derivative[J].Journal of Qiqihar University(Natural Science Edition),2013(1):52-55. |
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| Authors: | ZHENG Lin-lu YANG Fa-fu LIU Chao-hui |
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| Institution: | 1.Department of Chemistry,Ningde Normal College,Fujian Ningde 352100,China;2.College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China) |
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| Abstract: | A new bridged calix4]arene derivative containing semicarbazone groups and Schiff-base groups was designed and synthesized and its structure was confirmed by 1H NMR,MS and element analysis.Their binding properties for metal ions and amino acid were investigated.Experimental results showed that it possessed good extraction capabilities for cations and amino acid based on multifunctional complexation. |
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| Keywords: | calix[4]arene semicarbazide bridging complexation |
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