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Preparation of three-dimensional graphene foam for high performance supercapacitors
Authors:Yunjie Ping  Youning Gong  Qiang Fu and Chunxu Pan
Institution:School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072, China;School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072, China;School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072, China;School of Physics and Technology, and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072, China
Abstract:Supercapacitor is a new type of energy-storage device, and has been attracted widely attentions. As a two dimensional (2D) nanomaterials, graphene is considered to be a promising material of supercapacitor because of its excellent properties involving high electrical conductivity and large surface area. In this paper, the large-scale graphene is successfully fabricated via environmental-friendly electrochemical exfoliation of graphite, and then, the three dimensional (3D) graphene foam is prepared by using nickel foam as template and FeCl3/HCl solution as etchant. Compared with the regular 2D graphene paper, the 3D graphene foam electrode shows better electrochemical performance, and exhibits the largest specific capacitance of approximately 128 F/g at the current density of 1 A/g in 6 M KOH electrolyte. It is expected that the 3D graphene foam will have a potential application in the supercapacitors.
Keywords:Supercapacitor  3D graphene foam  2D graphene paper  Electrochemical performance
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