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基于卡尔曼滤波的差分光学吸收光谱法
引用本文:李素文,刘文清,谢品华.基于卡尔曼滤波的差分光学吸收光谱法[J].华南理工大学学报(自然科学版),2006,34(10):113-116,122.
作者姓名:李素文  刘文清  谢品华
作者单位:中国科学院,安徽光学精密机械研究所,安徽,合肥,230031
基金项目:国家863计划项目(2002AA641020),中科院知识创新工程重要方向项目(KJCX2-SW-H08)
摘    要:针对差分光学吸收光谱(DOAS)技术中气体吸收结构的重叠问题,提出利用卡尔曼滤波进行光谱校正.卡尔曼滤波是一种递推式的现代滤波方法,它在吸收结构严重重叠的情况下,仍可得到很好的分析结果.文中简介了差分光学吸收光谱法,分析了卡尔曼滤波原理,并应用卡尔曼滤波对大气中SO2的差分光学吸收光谱进行了研究,同时探讨了大气中NO2和O3对SO2测量的影响.实验结果表明,该方法可有效地校正重叠,提高了DOAS系统的精度.

关 键 词:差分光学吸收光谱  卡尔曼滤波  校正  重叠
文章编号:1000-565X(2006)10-0113-04
收稿时间:2005-09-12
修稿时间:2005-09-12

Differential Optical Absorption Spectroscopy Based on Kalman Filtering
Li Su-wen,Liu Wen-qing,Xie Pin-hua.Differential Optical Absorption Spectroscopy Based on Kalman Filtering[J].Journal of South China University of Technology(Natural Science Edition),2006,34(10):113-116,122.
Authors:Li Su-wen  Liu Wen-qing  Xie Pin-hua
Institution:Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, Anhui, China
Abstract:In order to overcome the overlapped absorption structures in differential optical absorption spectroscopy(DOAS),a method of spectrum correction based on Kalman filtering is developed.Kalman filtering,a modern recursive filtering,can correct disturbed spectrum signals even though the signals are strongly overlapped.This paper introduces DOAS in brief,analyzes the mechanism of Kalman filtering,Kalman filtering is applied to process the differential optical absorption spectrum of SO_2 in the atmosphere,meanwhile,the influence of NO_2 and O_3 on SO_2 is discussed in this paper.Experimental results indicate that the proposed method can effectively correct overlapping spectra and greatly improve the accuracy of DOAS system.
Keywords:differential optical absorption spectroscopy  Kalman filtering  correction  overlapping
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