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超声处理下沸石/TiO2复合体光催化剂性能及结构
引用本文:明彩兵,吴平霄,叶代启.超声处理下沸石/TiO2复合体光催化剂性能及结构[J].华南理工大学学报(自然科学版),2005,33(12):14-18.
作者姓名:明彩兵  吴平霄  叶代启
作者单位:华南理工大学,环境科学与工程学院,广东,广州,510640;华南理工大学,环境科学与工程学院,广东,广州,510640;华南理工大学,环境科学与工程学院,广东,广州,510640
基金项目:国家自然科学基金资助项目(40202007);广东省自然科学基金资助项目(000623,020938,04020017);广东省重大科技计划项目(2001367,2002254)
摘    要:分别用经过和未经过超声处理而制备出的沸石 /TiO2复合体光催化剂对含甲苯废气进行光催化降解实验,并运用x射线定向衍射技术和红外光谱探讨了超声处理对沸石/TiO2复合体光催化剂性能及结构的影响.结果表明,超声处理降低了复合体光催化剂中TiO2的纳米颗粒粒径,并使复合体光催化剂中TiO2与沸石的结构羟基发生反应形成键合,从而增强了复合体的光催化活性,相应地提高了复合体光催化剂对甲苯的光催化降解率.

关 键 词:沸石/TiO2复合体  超声波  光催化性能  甲苯
文章编号:1000-565X(2005)12-0014-05
收稿时间:2004-12-02
修稿时间:2004年12月2日

Performance and Structure of Composite Zeolite/TiO2 Photocatalyst with Ultrasonic Treatment
Ming Cai-bing,Wu Ping-xiao,Ye Dai-qi.Performance and Structure of Composite Zeolite/TiO2 Photocatalyst with Ultrasonic Treatment[J].Journal of South China University of Technology(Natural Science Edition),2005,33(12):14-18.
Authors:Ming Cai-bing  Wu Ping-xiao  Ye Dai-qi
Institution:College of Environmental Science and Engineering, South China Univ. of Tech. , Guangzhou 510640, Guangdong, China
Abstract:The photocatalytic degradation of exhaust gas containing toluene was conducted by using the zeolite/TiO2 composites with and without ultrasonic treatment as the photocatalysts, and the influence of ultrasonic treatment on the photocatalytic performance and structure of zeolite/TiO2 composite was investigated by means of XRD and IR. The results indicate that the ultrasonic helps reduce the size of TiO2 nano-particles and causes the bonding reaction of TiO2 with the structure hydroxy in zeolite, thus resulting in the improvement of the photocatalytic, activity of zeolite/ TiO2 and the degradation rate of toluene under the action of zeolite/TiO2 composite.
Keywords:zeolite/TiO2 composite  ultrasonic  photocatalysis performance  Toluene
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