| 固-液相转移催化法合成4,4′-联苯撑二芳酰基硫脲衍生物 |
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| 引用本文： | 元瑛,魏太保,张有明,张五卷.固-液相转移催化法合成4,4′-联苯撑二芳酰基硫脲衍生物[J].甘肃联合大学学报(自然科学版),2000(Z2). |
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| 作者姓名： | 元瑛 魏太保 张有明 张五卷 |
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| 作者单位： | 甘肃省医疗器械质检站，西北师范大学化学系，西北师范大学化学系，西北师范大学化学系 甘肃兰州730000，甘肃 兰州730070，甘肃 兰州730070，甘肃 兰州730070 |
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| 摘 要： | 在固—液相转移催化条件下,以 PEG-600为催化剂,通过芳酰氯与硫氰酸铵反应合成了中间体芳酰基异硫氰酸酯;后者不经分离,分别与联苯二胺和邻甲联苯二胺反应,高产率获得相应的芳酰基硫脲衍生物,用元素分析,IR 和~1HNMR 光谱确定了其结构.
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| 关 键 词： | 4.4′-联苯撑二芳酰基硫脲衍生物 合成 固-液相转移催化 PEG-600 |
Synthesis of 4,4'-diphenylene-bis-aroyl thiourea derivatives under the condition of solid-Liquid phase tramsfer catalysis |
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| YUAN Ying Gansu Medical Equipment Guanlity Office,Lanzhou Gansu WEI Tai-bao ZHANG You-ming ZHANG Wu-juan.Synthesis of 4,4'-diphenylene-bis-aroyl thiourea derivatives under the condition of solid-Liquid phase tramsfer catalysis[J].Journal of Gansu Lianhe University :Natural Sciences,2000(Z2). |
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| Authors: | YUAN Ying Gansu Medical Equipment Guanlity Office Lanzhou Gansu WEI Tai-bao ZHANG You-ming ZHANG Wu-juan |
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| Institution: | YUAN Ying Gansu Medical Equipment Guanlity Office,Lanzhou Gansu 730000WEI Tai-bao ZHANG You-ming ZHANG Wu-juan Department of Chemistry,Northwest Normal University,Lanzhou Gansu 730070 |
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| Abstract: | Under the conditioin of solid-Liquid phase transfer catalysis,using PEG-600 as the catalyst,aroyl chloride reacts with ammoniam thiocyanate to give the intermediate aroyl isothiocyanate.The Latter does not need to be isolated and reacts with 4,4'-diaminobi phenyl and 2,2'-dimethyl-4,4'-diaminobiphenyl to give the corresponding aroyl thiourea derivatives in high yields.Their structures were confirmed by element analysis IR ad ~1HNMR. |
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