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邻菲啰啉在银电极表面的吸附方式和支持电解质对SERS光谱的影响研究
引用本文:顾仁敖,宗亚平,侍育军,冷永章.邻菲啰啉在银电极表面的吸附方式和支持电解质对SERS光谱的影响研究[J].苏州大学学报(医学版),1989(2).
作者姓名:顾仁敖  宗亚平  侍育军  冷永章
作者单位:苏州大学化学系,苏州大学化学系,苏州大学化学系,苏州大学激光研究室 88届毕业生
摘    要:本文通过测定邻菲啰啉分子(O-Phen)吸附在银电极表面的表面增强喇曼散射(SERS)光谱及不同支持电解质对邻菲啰啉分子吸附在银电极表面的SERS光谱的影响,探讨了邻菲啰啉分子在银电极表面的吸附方式和不同支持电解质在银电极表面的吸附能力。实验结果表明:O-Phen通过两个氮原子竖直吸附在银电极表面,不同支持电解质在银电极表面的吸附能力不同,且对邻菲啰啉分子的SERS效应的影响也不同。

关 键 词:吸附方式  表面增强喇曼散射  邻菲啰啉

EXPERIMENTAL STUDY OF THE ADSORPTION MODEL OF O-PHEN ADSORBED ON A SILVER ELECTRODE SURFACE AND THE EFFECT OF DIFFERENT SUPPORT ELECTROLYTES ON SERS SPECTRA
Gu Renao Zong Yaping Shi Yu.EXPERIMENTAL STUDY OF THE ADSORPTION MODEL OF O-PHEN ADSORBED ON A SILVER ELECTRODE SURFACE AND THE EFFECT OF DIFFERENT SUPPORT ELECTROLYTES ON SERS SPECTRA[J].Journal of Suzhou University(Natural Science),1989(2).
Authors:Gu Renao Zong Yaping Shi Yu
Institution:Gu Renao Zong Yaping Shi Yu(?)un(Chemistry Department)Leng Yong Zhang(Laser Research Section)
Abstract:This paper presents the study of the adsorption model of O-Phenanthroline (O-Phen) adsorbed on a silver electrode surface and the adsorptive ability of different support electrolytes adsorbed on the silver electrode by determining the SERS spectra of O-Phen adsorbed on the silver electrode and the effect of the different support electrolytes on the SERS spectra of O-phen adsorbed on the silver electrode, Experimental results show O-Phen adsorbed on the silver electrode surface via two nitrogen atoms, There are different adsorptive ability on the silver electrode surface for the different support electrolytes which give the different influence on the SERS effect of O-Phen
Keywords:adsorption model  surface enhanced Raman scattering  O-phenauthroline
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