| 烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH）的合成及催化性能初探 |
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| 引用本文： | 厉兰,吁诚铭,徐凡,沈琪.烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH）的合成及催化性能初探[J].苏州大学学报(医学版),2009,25(1):72-76. |
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| 作者姓名： | 厉兰 吁诚铭 徐凡 沈琪 |
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| 作者单位： | 苏州大学,化学化工学院,江苏省有机合成重点实验室,江苏,苏州215006
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| 摘 要： | 用定量加入NaOH的方法高产率地合成了烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH），并对其进行了X射线晶体结构鉴定．此外，将其对芳醛的Tishchenko反应的催化活性进行了初探．
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| 关 键 词： | 烷氧基 簇合物 催化 Tishchenko |
Synthesis of lanthanide-sodium alkoxide cluster SmNa_8(O~tBu)_(10)(OH) and its catalytic activity |
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| Li Lan,Yu Chengming,Xu Fan,Shen Qi.Synthesis of lanthanide-sodium alkoxide cluster SmNa_8(O~tBu)_(10)(OH) and its catalytic activity[J].Journal of Suzhou University(Natural Science),2009,25(1):72-76. |
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| Authors: | Li Lan Yu Chengming Xu Fan Shen Qi |
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| Institution: | Key Laboratory of Organic Synthesis of Jiangsu Province;School of Chemistry and Chemical Engineering;Suzhou Univ.;Suzhou 215006;China |
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| Abstract: | The lanthanide-sodium alkoxide cluster SmNa8(OtBu)10(OH) was synthesized in high yields by adding a certain amount of NaOH,and its structure was confirmed by X-ray.Moreover,its catalytic activity was tested for the Tishchenko reaction of aromatic aldehydes. |
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| Keywords: | Tishchenko |
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