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| 有机助剂对葡萄糖加氢反应中RU/C催化剂的影响 | |
| 引用本文： | 王向宇,梁丽珍,徐三魁,李利民.有机助剂对葡萄糖加氢反应中RU/C催化剂的影响[J].郑州大学学报(理学版),2005,37(4):80-83. |
| 作者姓名： | 王向宇 梁丽珍 徐三魁 李利民 |
| 作者单位： | 1. 郑州大学化学系,郑州,450001 2. 郑州大学化学系,郑州,450001;郑州航空工业管理学院,郑州,450015 3. 河南工业大学材料工程学院,郑州,450007 |
| 基金项目： | 河南省高校杰出科研创新人才工程项目 |
| 摘 要： | 考察了Ru/C催化剂制备过程中加入有机助剂对葡萄糖加氢反应活性、制备重现性和使用稳定性的影响.利用分光光度法考察了RuCl3在活性炭上的吸附量和吸附强度,并通过程序升温还原(TPR)技术,考察Ru/C催化剂的表面还原性质,探讨了Ru/C催化剂表面性能与催化剂活性的关联规律.结果表明,加入有机助剂不仅能增加Ru的吸附量和吸附强度,改善催化剂的表面性能,并明显提高了催化剂的活性、稳定性和制备重现性. |
| 关 键 词： | Ru/C催化剂 有机助剂 葡萄糖加氢 稳定性 |
| 文章编号： | 1671-6841(2005)04-0080-04 |
| 收稿时间： | 01 3 2005 12:00AM |
| 修稿时间： | 2005年1月3日 |
Influence of the Organic Promoters on Ru/C Catalyst for Glucose Hydrogenation |
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| Wang Xiangyu,Liang Lizhen,Xu Sankui,Li Limin.Influence of the Organic Promoters on Ru/C Catalyst for Glucose Hydrogenation[J].Journal of Zhengzhou University:Natural Science Edition,2005,37(4):80-83. | |
| Authors: | Wang Xiangyu Liang Lizhen Xu Sankui Li Limin |
| Institution: | 1. Department of Chemistry ,Zhengzhou University ,Zhengzhou 450001 ,China ; 2. Zhengzhou Institute of Aeronautical Industry Management ,Zhengzhou 450015 ,China ; 3. College of Materials Engineering, Henan University of Technology ,Zhengzhou 450007 ,China |
| Abstract: | The influence of the organic promoters on the activity of the Ru/C catalyst for glucose hydrogenation,the reproducibility of catalyst preparation and the long-term stability in the hydrogenation reaction are investigated.The absorption amount and absorption strength of RuCl_3 on carbon are determined by spectrophotometry.The surface properties of different Ru/C catalysts can be characterized by means of temperature programmed reduction(TPR),and the law relation with the hydrogenation activity is discussed.The results show that the addition of organic promoters not only increaes absorption amount of ruthenium,but also increases the absorption strength of ruthenium on the support,improves the surface properties of Ru/C catalysts and enhances the catalytic hydrogenation activity.Moreover,the catalysts modified with organic promoters show the long-term stability for glucose hydrogenation and the reproducibility of catalyst preparation. |
| Keywords: | Ru/C catalyst organic promoter glucose hydrogenation stability |
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