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小波变换用于示波计时电位法中重叠峰解析
引用本文:张红权,潘忠孝.小波变换用于示波计时电位法中重叠峰解析[J].西北大学学报,1999,29(4):313-316.
作者姓名:张红权  潘忠孝
作者单位:西北大学电分析化学研究所!陕西西安710069(张红权,郑建斌,仲红波),中国科学技术大学应用化学系!安徽合肥230026(潘忠孝,张懋森)
基金项目:国家自然科学基金,陕西省自然科学基金,陕西省教委专项科研基金,中国博士后基金
摘    要:基于小波变换的分频及时移不变性,将小波变换用于示波计时电位法中重叠峰解析的研究。探讨了极化电流大小、频率和示波信号中噪音、分解次数等因素对小波变换结果的影响。实验结果表明:小波变换能从含有噪音和背景的信号中提取有用信息,使信号中重叠峰获得了较好的分离,可用于多组分的定量分析。

关 键 词:化学计量学  信号处理  示波分析  小波变换  重叠峰解析

Investigation on application of w avelet transform in resolvingoverlapped peaks in oscillographic chronopotentiom etry
Z H A N G Hong quan,Z H E N G Jian bin,Z H O N G Hong bo,P A N Zhong xiao,Z H A N G Mao sen.Investigation on application of w avelet transform in resolvingoverlapped peaks in oscillographic chronopotentiom etry[J].Journal of Northwest University(Natural Science Edition),1999,29(4):313-316.
Authors:Z H A N G Hong quan  Z H E N G Jian bin  Z H O N G Hong bo  P A N Zhong xiao  Z H A N G Mao sen
Institution:Z H A N G Hong quan1,Z H E N G Jian bin1,Z H O N G Hong bo1,P A N Zhong xiao2,Z H A N G Mao sen2
Abstract:Based on properties of frequency decom position and tim e shift invariety of w avelet transform , thetransform w as applied in study ofresolving overlapped peaks in oscillographic chronopotentiom etry. Effectof polarized current, frequency, noise in oscillographic signal and decom position frequency on results ofw avelet transform w as investigated. Experim entalresults show ed that w avelet transform is able to recoveruseful inform ation from the osillographic signalw ith noise and background signal. Overlapped peaks in os cillographic chronopotentiom etry is resolved com pletely, w hich can be used in quantitative analysis of m ul ti com ponent.
Keywords:chem om etrics  signal processing  w avelet transform  oscillographic analysis  resolution ofoverlapped peaks
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