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防煤自燃聚乙烯醇泡沫材料的制备及性能
引用本文:孟献梁,张静,刘亚菲,张中彩,吴国光,褚睿智,王志华.防煤自燃聚乙烯醇泡沫材料的制备及性能[J].西安科技大学学报,2011,31(6).
作者姓名:孟献梁  张静  刘亚菲  张中彩  吴国光  褚睿智  王志华
作者单位:1. 中国矿业大学煤矿瓦斯与火灾防治教育部重点实验室,江苏徐州 221008;中国矿业大学化工学院,江苏徐州 221008
2. 中国矿业大学化工学院,江苏徐州,221008
基金项目:国家自燃科学基金,中央高校基本科研业务费专项资金项目,中国矿业大学煤矿瓦斯与火灾防治教育部重点实验室开放基金
摘    要:为防止煤炭自燃,采用隔氧性能优良的聚乙烯醇(PVA)为基料,添加改性剂、促凝剂和发泡剂制备了PVA隔氧泡沫材料,并对其隔氧性能和稳定性进行了研究.实验得到最优的PVA隔氧泡沫材料配方(wB%)为:94.81%水、4% PVA,1%改性剂A,0.15%促凝剂B和0.04%3#发泡剂;模拟煤炭堆储条件,对聚乙烯醇隔氧泡沫材料的隔氧性能和稳定性进行了40d测定.结果表明,此PVA隔氧泡沫材料能有效阻隔氧气进入,使箱体中氧气浓度从21%降至5%以下,并且实验前后PVA隔氧泡沫材料状况良好,无破损.

关 键 词:煤炭自燃  聚乙烯醇  隔氧泡沫材料

Preparation and properties of polyvinyl alcohol oxygeninsulating foam material to prevent coal spontaneous combustion
MENG Xian-liang,ZHANG Jing,LIU Ya-fei,ZHANG Zhong-cai,WU Guo-guang,CHU Rui-zhi,WANG Zhi-hua.Preparation and properties of polyvinyl alcohol oxygeninsulating foam material to prevent coal spontaneous combustion[J].JOurnal of XI’an University of Science and Technology,2011,31(6).
Authors:MENG Xian-liang  ZHANG Jing  LIU Ya-fei  ZHANG Zhong-cai  WU Guo-guang  CHU Rui-zhi  WANG Zhi-hua
Institution:MENG Xian-liang1,2,ZHANG Jing2,LIU Ya-fei2,ZHANG Zhong-cai2,WU Guo-guang2,CHU Rui-zhi2,WANG Zhi-hua2 (1.Key Laboratory of Gas and Fire Control for Coal Mines,China University of Mining & Technology,Ministry of Education,Xuzhou 221008,China,2.School of Chemical Engineering and Technology,China)
Abstract:In order to develop a new material to prevent the spontaneous combustion of coal,the modifiers,coagulant agents and foaming agents were used to modify the polyvinyl alcohol(PVA) which is an excellent oxygen-insulating material.Then the oxygen-insulating characteristics and the stability of the PVA foam material were investigated.The optimum formulation of foam material(wt %) is 94.81% water,4% PVA,1% modifier A,0.15% coagulant agent B and 0.04% foaming agent.Simulated coal pile storage conditions,the oxygen...
Keywords:spontaneous combustion of coal  polyvinyl alcohol  oxygen-insulating foam material  
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