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Cu/TiO2光催化还原硝酸根
引用本文:缪应纯,王刚,刘树云,吴世鹏.Cu/TiO2光催化还原硝酸根[J].曲靖师专学报,2013(6):31-35.
作者姓名:缪应纯  王刚  刘树云  吴世鹏
作者单位:曲靖师范学院资源与环境化学重点实验室,云南曲靖655011
基金项目:云南省应用基础研究计划自筹项目(2013FZ109);曲靖师范学院大学生创新性实验计划.
摘    要:以TiCl3为原料,通过喷雾干燥法一步合成锐钛矿Cu/TiO2,并用于紫外光下还原硝酸根.利用XRD,SEM,TEM,紫外可见漫反射等研究样品的性质.该方法合成的锐钛矿Cu/TiO2,铜以Cu+的形式存在.制备的2% Cu/TiO2催化剂活性最佳,反应240 min后,硝酸盐转化率为31%,氮气的选择性为56%.

关 键 词:光催化  二氧化钛  Cu掺杂  还原  硝酸盐

Photocatalytic Reduction of Nitrate in Underground Water over Cu/TiO2
Authors:Miao Yingchun  Wang Gang  Liu Shuyun  Wu Shipeng
Institution:(Facuhy of Chemical and Life Sciences, Key Laboratory of Environment Chemistry for Natural Resource, Qujing Normal University, Qujing Yunnan 655011, P. R. China)
Abstract:Cu/TiO2 facilely synthesized from TiC13 by aerosol - spraying preparation. XRD, UV - vis spectroscopy, N2 adsorption, XP spectra were used to characterize the prepared samples. The existence of Cu ions in the anatase TiO2 sample was demonstrated. The 2% Cu/TiO2 exhibited the best photocatalytic activity for nitrate reduction. The nitrate conversion was up to 31%, and the selectivity of N2 was 56% after reaction for 240 min.
Keywords:photocatalytic catalysis  titanium dioxide  Cu - doping  reduction  nitrate
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