| 配位聚合物的绿色化合成 |
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| 引用本文： | 陈金喜,张若冰.配位聚合物的绿色化合成[J].东南大学学报(自然科学版),2011,41(4):889-896. |
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| 作者姓名： | 陈金喜 张若冰 |
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| 作者单位： | 东南大学化学化工学院,南京,211189 |
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| 基金项目： | 江苏省自然科学基金资助项目(BK2009262); 教育部留学回国人员科研启动基金资助项目 |
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| 摘 要： | 为了使配位聚合物能够得到高效、绿色化的制备,近几年来该化合物的合成中引入了微波法、超声波法、固相反应法等,相比常规的水热/溶剂热、扩散法等方法,这些方法具有高效、简便、绿色等优点.固相反应法可以快速、定量地生成产物,并且通过改变其反应条件实现对配位聚合物的控制合成；微波法能够在很短的时间内制备出粒径可控的配位聚合物,也...
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| 关 键 词： | 配位聚合物 绿色化学 固相反应 超声波法 微波法 |
Green synthetic approaches of coordination polymers |
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| Chen Jinxi,Zhang Ruobing.Green synthetic approaches of coordination polymers[J].Journal of Southeast University(Natural Science Edition),2011,41(4):889-896. |
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| Authors: | Chen Jinxi Zhang Ruobing |
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| Institution: | Chen Jinxi Zhang Ruobing(School of Chemistry and Chemical Engineering,Southeast University,Nanjing 211189,China) |
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| Abstract: | Green synthetic approaches,such as solid-state reaction synthesis,microwave synthesis and ultrasonic synthesis are employed in recent years to prepare coordination polymers,which are more efficient,convenient,and environment-friendly than conventional methods.The solid-state reaction synthesis is able to produce products quickly in a quantitative manner,and by adjusting the reaction conditions,rational control can be achieved.Thus specific attention is given to this approach as it is a promising way toward ... |
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| Keywords: | coordination polymers green chemistry solid-state reactions ultrasonic synthesis microwave synthesis |
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