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水蒸气活化制备生物质活性炭的实验研究
引用本文:李勤,金保升,黄亚继,仲兆平,李斌,孙宇.水蒸气活化制备生物质活性炭的实验研究[J].东南大学学报(自然科学版),2009,39(5).
作者姓名:李勤  金保升  黄亚继  仲兆平  李斌  孙宇
作者单位:东南大学能源与环境学院,南京,210096
基金项目:国家重点基础研究发展计划(973计划)资助项目,国家自然科学基金资助项目,教育部博士点基金资助项目,东南大学优秀青年教师资助项目 
摘    要:以稻壳、花生壳和玉米芯为原料,采用物理活化法以水蒸气为活化剂制备得到活性炭.分析了水蒸气活化机理,并通过对活性炭得率高低、亚甲基蓝脱色效果强弱的比较,讨论了活化时间(t)、活化温度(T)和水蒸气流量(QH2O)对活性炭的炭活化得率(Cyield)和吸附性能的影响.实验结果表明:随着t的延长和T的升高,3种原料制得的Cyield不断降低,活性炭的吸附性能先升高后降低;随着QH2O的增加,Cyield先降低后升高,活性炭的吸附性能先升高后降低.通过比较,得出玉米芯是3种原料中最佳的制备活性炭的物质,其最佳工艺条件为T=800 ℃,t=90 min 和QH2O=15 mL/h,所制备的活性炭得率为26.18%,亚甲基蓝吸附值为150 mL/g,比表面积为924.48 m2/g,孔平均尺寸为2.4 nm.

关 键 词:生物质  活性炭  水蒸气活化

Preparation of biomass activated carbon by steam activation
Li Qin,Jin Baosheng,Huang Yaji,Zhong Zhaoping,Li Bin,Shun Yu.Preparation of biomass activated carbon by steam activation[J].Journal of Southeast University(Natural Science Edition),2009,39(5).
Authors:Li Qin  Jin Baosheng  Huang Yaji  Zhong Zhaoping  Li Bin  Shun Yu
Institution:Li Qin Jin Baosheng Huang Yaji Zhong Zhaoping Li Bin Shun Yu(School of Energy , Environment,Southeast University,Nanjing 210096,China)
Abstract:Biomass activated carbon prepared from rice hulls,peanut shell and corn cob by steam activation were studied.The reaction mechanism of the yield of activated carbon(Cyield) is discussed.Experimental results show that the effects of activation temperature,activation time and flowrate of steam on the adsorption properties were investigated by comparing the yield of Cyield,methylene blue(MB) adsorption.The yield of Cyield decreases and adsorption performance increases first and then decreases with the increase...
Keywords:biomass  activated carbon  steam activation  
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