| 对甲苯磺酰氨基酸甲醇或2,2-联吡啶混配Cu(II)配合物的电化学合成及表征 |
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| 引用本文： | 张秀梅,高伟,褚道葆.对甲苯磺酰氨基酸甲醇或2,2-联吡啶混配Cu(II)配合物的电化学合成及表征[J].安徽师范大学学报(自然科学版),2007(2). |
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| 作者姓名： | 张秀梅 高伟 褚道葆 |
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| 作者单位： | 桐城师范高等专科学校 安徽桐城231400(张秀梅，高伟)，安徽师范大学化学与材料科学学院 安徽芜湖241000(褚道葆) |
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| 基金项目： | 国家自然科学基金(No.20476001)，安徽省自然科学基金(No.00045317)资助 |
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| 摘 要： | 采用金属Cu为“牺牲阳极”,在含配体对甲苯磺酰L-异亮氨基酸(H2L)的甲醇溶液中电解合成了Cu(L)(2CH3OH)]配合物.当向含配体的甲醇溶液中加入2,2′-联吡啶时,电解合成了Cu(L)(2,2’-bipy)]配合物.利用元素分析、红外光谱、紫外光谱、热分析对配合物进行了表征.测试了铜电极在溶液中的电化学行为和配合物的电化学性质.
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| 关 键 词： | 金属铜配合物 电化学合成 “牺牲”阳极法 对甲基苯磺酰L-异亮氨基酸 |
Electrochemical Synthesis and Characterization of Transition Metal Cu(II) Complexes with Ttosyl-L-Isoleucine Ligand Methanol or 2,2'-Bipyridyl |
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| ZHANG Xiu-mei,GAO Wei,CHU Dao-bao.Electrochemical Synthesis and Characterization of Transition Metal Cu(II) Complexes with Ttosyl-L-Isoleucine Ligand Methanol or 2,2''''-Bipyridyl[J].Journal of Anhui Normal University(Natural Science Edition),2007(2). |
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| Authors: | ZHANG Xiu-mei GAO Wei CHU Dao-bao |
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| Institution: | ZHANG Xiu-mei1,GAO Wei1,CHU Dao-bao2 |
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| Abstract: | The direct electrosynthesis of Cu(II)complexes of tosyl-L-isoleucine,methanol was accomplished by electrochemical dissolution of sacrificial copper anodes in a methanol solution.When 2,2'-bipyridyl was added to the electrolyte solution a complex of Cu(L)(2,2'-bipy)] was obtained.The complexes were characterized by FT-IR,elemental analysis,UV-Visible spectra and thermal analysis.The electrochemical properties of the complexes and the electrochemical behaviors of metal electrode in electrolyte solution were examined. |
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| Keywords: | Cu(II) complexes electrochemical synthesis "Sacrificial" anodes method tosyl-L-isoleucine |
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