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二氧化碳对高碱值石油磺酸镁质量的影响
引用本文:丁丽芹,何力,付兴国,梁生荣.二氧化碳对高碱值石油磺酸镁质量的影响[J].西安石油大学学报(自然科学版),2004,19(2):45-48.
作者姓名:丁丽芹  何力  付兴国  梁生荣
作者单位:1. 西安石油大学,化学化工学院,陕西,西安,710065
2. 中国石油润滑油分公司,北京,100101
摘    要:在 CO2 存在下进行的碳酸化过程 ,又称过碱度化过程 ,是合成高碱值石油磺酸镁金属化工艺的关键步骤 .研究发现 :对特定的 Mg O及特定的反应物体系 ,存在一临界碳酸化速率和最佳的CO2 通入量 ,从而为进一步研制高碱值石油磺酸镁奠定了基础

关 键 词:润滑油添加剂  清净剂  碱值  石油磺酸镁  碳酸化
文章编号:1001-5361(2004)02-0045-03
修稿时间:2003年9月7日

Effects of carbon dioxide on the quality of overbased magnesium petroleum sulphonate
DING Li-qin,HE Li,FU Xing-guo,et al.Effects of carbon dioxide on the quality of overbased magnesium petroleum sulphonate[J].Journal of Xian Shiyou University,2004,19(2):45-48.
Authors:DING Li-qin  HE Li  FU Xing-guo  
Abstract:The carbonating process under the existence of carbon dioxide, also being named overbasing process, is a key step to the synthesis of overbased magnesium petroleum sulphonate. The effects of the rate of carbon dioxide supply on the quality of the product of the process are discussed, and it is found that to a specific magnesium oxide and a specific reaction system, there is an optimal rate of carbon dioxide supply, or critical carbonating rate, and when carbon dioxide is supplied at the rate, the base number and viscosity of the product are the greatest, the precipitate after carbonation is the least. To the magnesium oxide and the reaction system in this study, the critical carbonating rate is 120 mL/min. The effects of the volume of carbon dioxide supply on the quality of the product are studied at the critical carbonating rate, and it is found that when the actual supply volume is 1.5 times of theoretical supply volume, the base number and viscosity of the product are the greatest, and the precipitate after carbonation is the least.
Keywords:lubricating oil additive  detersive  overbase number  carbonation  magnesium petroleum sulphonate
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