| Polanyi吸附势理论的热力学推导 |
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| 引用本文： | 刘保安,董云会,刘晓芳.Polanyi吸附势理论的热力学推导[J].济南大学学报(自然科学版),1999,9(2):105. |
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| 作者姓名： | 刘保安 董云会 刘晓芳 |
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| 作者单位： | 淄博学院材料工程系!山东淄博，255200 |
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| 摘 要： | 运用热力学理论和溶液理论，在不受经验性假设限制的条件下，分析了Polanyi吸附势的热力学含义，推导出固液界面吸附的基本条件、凝聚吸附条件、混合溶液竞争凝聚吸附以及顶替吸附的基本条件，并得出与Polanyi吸附势理论及其在溶液中吸附的应用相一致的结果。
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| 关 键 词： | 吸附 吸附势 固-液吸附 |
Briefly Deduced of Polanyi Adsorption Potential Theroy |
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| Liu Bao''an,Dong Yunhui,Liu Xiaofang.Briefly Deduced of Polanyi Adsorption Potential Theroy[J].Journal of Jinan University(Science & Technology),1999,9(2):105. |
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| Authors: | Liu Bao'an Dong Yunhui Liu Xiaofang |
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| Abstract: | Based on thermodynamics and solution theory,this paper analyzes the thermodynamics meaning of Polanyi adsorption Potential without the limitation of experiential suppose, educes the postulate of adsorption on solidityliquid interface, the condition of agglomerate adsorption, the postulate of competitive agglomerate adsorption in the mixed solutinn and substitute adsorption. The result is accordant to Polanyi enlarges the applied range of this theory and will conduce to lucubration on solution adsorption theory, |
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| Keywords: | adsorption adsorption potential solid-liquid adsorption |
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